中文名 | 2,3,4,6-四-O-乙酰基-Alpha-D-吡喃半乳糖酰基-2,2,2-三氯代亚氨乙酸酯 |
---|---|
英文名 | [(2R,3S,4S,5R,6R)-3,4,5-triacetyloxy-6-(2,2,2-trichloroethanimidoyl)oxyoxan-2-yl]methyl acetate |
中文别名 | 2,3,4,6-四-O-乙酰基-Α-D-吡喃半乳糖酰基-2,2,2-三氯代亚氨乙酸酯 |
英文别名 |
(2R,3S,4S,5R,6R)-2-(acetoxymethyl)-6-(3-(4,4,5,5-tetramethyl-1,3-dioxolan-2-yl)propoxy)tetrahydro-2H-pyran-3,4,5-triyl triacetate
2,3,4,6-Tetra-O-acetyl-a-D-galactopyranosyl trichloroacetimidate |A-D-Galactopyranose,2,3,4,6-Tetraacetate 1-(2,2,2-Trichloroethanimidate) |
密度 | 1.558g/cm3 |
---|---|
沸点 | 463.341ºC at 760 mmHg |
熔点 | 121ºC |
分子式 | C16H20Cl3NO10 |
分子量 | 492.69000 |
闪点 | 234.02ºC |
精确质量 | 491.01500 |
PSA | 147.51000 |
LogP | 1.53330 |
外观性状 | 固体;White to Light yellow powder to crystal |
折射率 | 1.552 |
储存条件 | Freezer |
2,3,4,6-Tetra-O-acetyl-α-D-galactopyranosyl 2,2,2-
Revision number: 5
Trichloroacetimidate SAFETY DATA SHEET Section1. IDENTIFICATION 2,3,4,6-Tetra-O-acetyl-α-D-galactopyranosyl 2,2,2-Trichloroacetimidate Product name: Revision number:5 Section2. HAZARDS IDENTIFICATION GHS classification Not classified PHYSICAL HAZARDS HEALTH HAZARDSNot classified Not classified ENVIRONMENTAL HAZARDS GHS label elements, including precautionary statements None Pictograms or hazard symbols Signal wordNo signal word None Hazard statements Precautionary statements:None Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substance/mixture:Substance Components:2,3,4,6-Tetra-O-acetyl-α-D-galactopyranosyl 2,2,2-Trichloroacetimidate Percent:>93.0%(LC) CAS Number:86520-63-0 Chemical Formula:C16H20Cl3NO10 Section4. FIRST AID MEASURES Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. Skin contact:Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation or rash occurs: Get medical advice/attention. Eye contact:Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion:Get medical advice/attention if you feel unwell. Rinse mouth. Protection of first-aiders:A rescuer should wear personal protective equipment, such as rubber gloves and air- tight goggles. Section5. FIRE-FIGHTING MEASURES Suitable extinguishingDry chemical, foam, water spray, carbon dioxide. media: Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to from the chemical:generate poisonous fume. 2,3,4,6-Tetra-O-acetyl-α-D-galactopyranosyl 2,2,2-Trichloroacetimidate Section5. FIRE-FIGHTING MEASURES Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. In case of fire in the surroundings: Remove movable containers if safe to do so. When extinguishing fire, be sure to wear personal protective equipment. Special protective equipment for firefighters: Section6. ACCIDENTAL RELEASE MEASURES Personal precautions,Use personal protective equipment. Keep people away from and upwind of spill/leak. protective equipment and Entry to non-involved personnel should be controlled around the leakage area by emergency procedures: roping off, etc. Environmental precautions: Prevent product from entering drains. Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it. containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with up: appropriate laws and regulations. Section7. HANDLING AND STORAGE Precautions for safe handling Technical measures:Handling is performed in a well ventilated place. Wear suitable protective equipment. Prevent dispersion of dust. Wash hands and face thoroughly after handling. Use a local exhaust if dust or aerosol will be generated. Advice on safe handling: Avoid contact with skin, eyes and clothing. Conditions for safe storage, including any incompatibilities Storage conditions:Keep container tightly closed. Store in a freezer. Store away from incompatible materials such as oxidizing agents. Heat-sensitive Packaging material:Comply with laws. Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls:Install a closed system or local exhaust as possible so that workers should not be exposed directly. Also install safety shower and eye bath. Personal protective equipment Respiratory protection: Dust respirator. Follow local and national regulations. Hand protection:Protective gloves. Eye protection:Safety glasses. A face-shield, if the situation requires. Skin and body protection: Protective clothing. Protective boots, if the situation requires. Section9. PHYSICAL AND CHEMICAL PROPERTIES Physical state (20°C):Solid Form:Crystal- Powder Colour:Very pale yellow - Pale yellow Odour:No data available pH: No data available Melting point/freezing point:122°C Boiling point/range:No data available Flash point:No data available Flammability or explosive limits: No data available Lower: Upper:No data available No data available Relative density: Solubility(ies): [Water]No data available [Other solvents]No data available 2,3,4,6-Tetra-O-acetyl-α-D-galactopyranosyl 2,2,2-Trichloroacetimidate Section10. STABILITY AND REACTIVITY Stable under proper conditions. Chemical stability: Possibility of hazardous No special reactivity has been reported. reactions: Incompatible materials: Oxidizing agents Hazardous decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx), Hydrogen chloride products: Section11. TOXICOLOGICAL INFORMATION Acute Toxicity:No data available Skin corrosion/irritation: No data available Serious eyeNo data available damage/irritation: Germ cell mutagenicity: No data available Carcinogenicity: IARC =No data available NTP =No data available Reproductive toxicity:No data available Section12. ECOLOGICAL INFORMATION Ecotoxicity: Fish:No data available No data available Crustacea: Algae:No data available Persistence / degradability: No data available BioaccumulativeNo data available potential(BCF): Mobility in soil No data available Log Pow: Soil adsorption (Koc):No data available No data available Henry's Law constant(PaM3/mol): Section13. DISPOSAL CONSIDERATIONS Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when disposing of the substance. Section14. TRANSPORT INFORMATION Does not correspond to the classification standard of the United Nations Hazards Class: UN-No:Not listed Section15. REGULATORY INFORMATION Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002 and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were prescribed. 2,3,4,6-Tetra-O-acetyl-α-D-galactopyranosyl 2,2,2-Trichloroacetimidate SECTION 16 - ADDITIONAL INFORMATION N/A |
~99% 86520-63-0 |
文献:Ban, Lan; Mrksich, Milan Angewandte Chemie - International Edition, 2008 , vol. 47, # 18 p. 3396 - 3399 |
~92% 86520-63-0 |
文献:Pilgrim, Wayne; Murphy, Paul V. Journal of Organic Chemistry, 2010 , vol. 75, # 20 p. 6747 - 6755 |
~39% 86520-63-0 |
文献:Carbohydrate Research, , vol. 150, p. 199 - 212 |
~% 86520-63-0 |
文献:Carbohydrate Research, , vol. 341, # 11 p. 1954 - 1964 |
~% 86520-63-0 |
文献:European Journal of Organic Chemistry, , # 14 p. 2697 - 2705 |
~% 86520-63-0 |
文献:Journal of the American Chemical Society, , vol. 129, # 12 p. 3586 - 3597 |
~% 86520-63-0 |
文献:Carbohydrate Research, , vol. 320, # 3-4 p. 147 - 160 |
上游产品 4 | |
---|---|
下游产品 4 | |