6131-59-5

• 常用中文名：(R)-2-甲氧基-1-丙醇
• 常用英文名：(R)-2-METHOXYPROPAN-1-OL
• CAS号：6131-59-5
• 分子式：C₄H₁₀O₂
• 分子量：90.121
• 发布时间：2018-03-04 08:00:00
• 更新时间：2024-01-11 16:37:02

名称

• 中文名: (R)+ 2-甲氧在-1-丙醇
• 英文名: (2R)-2-methoxypropan-1-ol
• 英文别名: 2-methoxy-1-propanol; (2R)-2-Methoxy-1-propanol; (2R)-2-Methoxypropan-1-ol; 1-Propanol, 2-methoxy-, (2R)-

物化性质

• 密度: 0.9±0.1 g/cm3
• 沸点: 130.0±0.0 °C at 760 mmHg
• 分子式: C₄H₁₀O₂
• 分子量: 90.121
• 闪点: 41.9±7.7 °C
• 精确质量: 90.068077
• PSA: 29.46000
• LogP: -0.45
• 蒸汽压: 4.4±0.5 mmHg at 25°C
• 折射率: 1.397
• 储存条件: 2-8°C

MSDS

Name: 344(R)-(-)-2-Methoxypropanol Material Safety Data Sheet Synonym: None Known CAS: 6131-59-5 Section 1 - Chemical Product MSDS Name:344(R)-(-)-2-Methoxypropanol Material Safety Data Sheet Synonym:None Known Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 6131-59-5 (R)-(-)-2-Methoxypropanol ca. 100 unlisted Hazard Symbols: None Listed. Risk Phrases: 10 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Flammable.The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. May cause chemical conjunctivitis and corneal damage. Skin: May cause irritation and dermatitis. May cause cyanosis of the extremities. Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. Ingestion of large amounts may cause CNS depression. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Aspiration may lead to pulmonary edema. Vapors may cause dizziness or suffocation. Inhalation at high concentrations may cause CNS depression and asphixiation. May cause burning sensation in the chest. Chronic: Effects may be delayed. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes. Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air. Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Flammable liquid and vapor. Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Use agent most appropriate to extinguish fire. Do NOT use straight streams of water. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use with adequate ventilation. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Storage: Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels. Exposure Limits CAS# 6131-59-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Respirators: Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: 33 deg C ( 91.40 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: 0.938 Molecular Formula: CH3CH(OCH3)CH2CH Molecular Weight: 90.12 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, ignition sources, excess heat. Incompatibilities with Other Materials: Acid chlorides, oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 6131-59-5 unlisted. LD50/LC50: Not available. Carcinogenicity: (R)-(-)-2-Methoxypropanol - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: FLAMMABLE LIQUID, N.O.S.* Hazard Class: 3 UN Number: 1993 Packing Group: III IMO Shipping Name: FLAMMABLE LIQUID, N.O.S. Hazard Class: 3.2 UN Number: 1993 Packing Group: III RID/ADR Shipping Name: FLAMMABLE LIQUID, N.O.S. Hazard Class: 3 UN Number: 1993 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: R 10 Flammable. Safety Phrases: S 9 Keep container in a well-ventilated place. S 16 Keep away from sources of ignition - No smoking. S 24 Avoid contact with skin. S 33 Take precautionary measures against static discharges. WGK (Water Danger/Protection) CAS# 6131-59-5: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 6131-59-5 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 6131-59-5 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi
• 海关编码: 2909499000

合成路线

40105-20-2 ~60% 6131-59-5

文献：Condon, Stephen M.; Jackson, Randy William; Laporte, Matthew G.; Burns, Christopher J.; Herbertz, Torsten; Gaboury, Janet A. Patent: US2007/219212 A1, 2007 ; Location in patent: Page/Page column 22 ;

67-56-1 16088-62-3 ~43% 4984-22-9 6131-59-5 详细

文献：Chemical Communications, , # 11 p. 1287 - 1289

4324-39-4 ~% 116422-39-0 6131-59-5

文献：Journal of the Chemical Society - Perkin Transactions 1, , # 12 p. 1467 - 1479

67-56-1 15448-47-2 ~% 26550-55-0 4984-22-9 详细

文献：Chemistry - A European Journal, , vol. 3, # 12 p. 2063 - 2070

67-56-1 16088-62-3 ~% 26550-55-0 4984-22-9 详细

文献：Chemistry - A European Journal, , vol. 3, # 12 p. 2063 - 2070

上下游产品

上游产品  4
67-56-1 16088-62-3 4324-39-4 15448-47-2
下游产品  0

海关

海关编码	2909499000
中文概述	2909499000 其他醚醇及其卤化、磺化、硝化或亚硝化衍生物. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2909499000. ether-alcohols and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:9.0%. . MFN tariff:5.5%. General tariff:30.0%