英文名 | chloro-[chloro(methyl)alumanyl]oxy-methylalumane |
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英文别名 | 1,3-Dichloro-1,3-dimethyldialuminoxane solution |
分子式 | C2H16Al2Cl2O |
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分子量 | 181.01700 |
精确质量 | 180.02100 |
PSA | 9.23000 |
Date Updated: 13/FEB/2006
Version 1.4 Regulation (EC) No 1907/2006 ________________________________________________________________________ 1 - Product and Company Information ________________________________________________________________________ Product Name1,3-DICHLORO-1,3-DIMETHYLDIALUMINOXANE,
0.5M SOLUTION IN TOLUENE Product Number414425 Company Century Ba-Shi Building 22A-B, 200020 Shanghai Technical Phone #86-21-61415566 Fax 86-21-61415567 E-mail Address ________________________________________________________________________ 2 - Hazards Identification ________________________________________________________________________ SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT Highly flammable. Reacts violently with water. Toxic by inhalation, in contact with skin and if swallowed. Causes burns. ________________________________________________________________________ 3 - Composition/Information on Ingredients ________________________________________________________________________ Product NameCAS #EC noAnnex I Index Number 1,3-DICHLORO-1,3-DIMETHYLDIALUMINO 87043-37-6 NoneNone XANE,0.5M SOLUTION IN TOLUENE FormulaC2H6Al2Cl2O Molecular Weight 170,9400 AMU ________________________________________________________________________ 4 - First Aid Measures ________________________________________________________________________ AFTER INHALATION If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. AFTER INGESTION If swallowed, wash out mouth with water provided person is conscious. Call a physician. ________________________________________________________________________ 5 - Fire Fighting Measures ________________________________________________________________________ EXTINGUISHING MEDIA Suitable: Carbon dioxide, dry chemical powder, or appropriate foam. Unsuitable: Do not use water. SPECIAL RISKS Specific Hazard(s): Extremely flammable. Vapor may travel considerable distance to source of ignition and flash back. Explosion Hazards: Vapor may travel considerable distance to source of ignition and flash back. Container explosion may occur under fire conditions. SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. SPECIFIC METHOD(S) OF FIRE FIGHTING Use water spray to cool fire-exposed containers. ________________________________________________________________________ 6 - Accidental Release Measures ________________________________________________________________________ PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL Evacuate area. Shut off all sources of ignition. PROCEDURE(S) OF PERSONAL PRECAUTION(S) Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves. METHODS FOR CLEANING UP Cover with an activated carbon adsorbent, take up and place in closed containers. Transport outdoors. Ventilate area and wash spill site after material pickup is complete. ________________________________________________________________________ 7 - Handling and Storage ________________________________________________________________________ HANDLING Directions for Safe Handling: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE Conditions of Storage: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. Incompatible Materials: Do not allow contact with water ________________________________________________________________________ 8 - Exposure Controls / Personal Protection ________________________________________________________________________ ENGINEERING CONTROLS Safety shower and eye bath. Use only in a chemical fume hood. GENERAL HYGIENE MEASURES Wash thoroughly after handling. Wash contaminated clothing before reuse. PERSONAL PROTECTIVE EQUIPMENT Special Protective Measures: Wear appropriate government approved respirator, chemical-resistant gloves, safety goggles, other protective clothing. ________________________________________________________________________ 9 - Physical and Chemical Properties ________________________________________________________________________ pH N/A BP/BP Range111,000 °C MP/MP RangeN/A Flash Point- 11,000 °C.Method: closed cup FlammabilityN/A Autoignition TempN/A Oxidizing Properties N/A Explosive Properties N/A Explosion LimitsN/A Vapor PressureN/A SG/Density0,8830 g/cm3 Partition Coefficient N/A ViscosityN/A Vapor DensityN/A Saturated Vapor Conc. N/A Evaporation RateN/A Bulk DensityN/A Decomposition Temp.N/A Solvent ContentN/A Water ContentN/A Surface TensionN/A ConductivityN/A Miscellaneous DataN/A SolubilityN/A ________________________________________________________________________ 10 - Stability and Reactivity ________________________________________________________________________ STABILITY Reactions to Avoid: Reacts violently with: Materials to Avoid: Oxidizing agents, Water. HAZARDOUS DECOMPOSITION PRODUCTS Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide, Hydrogen chloride gas, Aluminum oxide. ________________________________________________________________________ 11 - Toxicological Information ________________________________________________________________________ SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Inhalation studies on toluene have demonstrated the development of inflammatory and ulcerous lesions of the penis, prepuce, and scrotum in animals. Exposure to and/or consumption of alcohol may increase toxic effects. ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. TARGET ORGAN INFORMATION Brain. Bladder. Kidneys. Liver. CONDITIONS AGGRAVATED BY EXPOSURE May cause nervous system disturbances. ________________________________________________________________________ 12 - Ecological Information ________________________________________________________________________ No data available. ________________________________________________________________________ 13 - Disposal Considerations ________________________________________________________________________ SUBSTANCE DISPOSAL Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Observe all federal, state, and local environmental regulations. ________________________________________________________________________ 14 - Transport Information ________________________________________________________________________ RID/ADR UN#: 3399 Class: 4.3 PG: I Subrisk: 3 Proper Shipping Name: Organometallic substance, liquid, water-reactive, flammable IMDG UN#: 3399 Class: 4.3 PG: I Subrisk: 3 Proper Shipping Name: Organometallic substance, liquid, water-reactive, flammable Marine Pollutant: No Severe Marine Pollutant: No Technical Name: Required IATA UN#: 3399 Class: 4.3 PG: I Subrisk: 3 Proper Shipping Name: Organometallic substance, liquid, water-reactive, flammable Inhalation Packing Group I: No Technical Name: Required ________________________________________________________________________ 15 - Regulatory Information ________________________________________________________________________ CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES INDICATION OF DANGER: F-C Highly Flammable. Corrosive. R-PHRASES: 11-14-23/24/25-34 Highly flammable. Reacts violently with water. Toxic by inhalation, in contact with skin and if swallowed. Causes burns. S-PHRASES: 16-26-36/37/39-45 Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Caution: Substance not yet fully tested (EU). ________________________________________________________________________ 16 - Other Information ________________________________________________________________________ WARRANTY The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. unlimitedpaper copies for internal use only. DISCLAIMER For R&D use only. Not for drug, household or other uses. 模块 15 - 法规信息 N/A 模块16 - 其他信息 N/A |
风险声明 (欧洲) | 11-14-23/24/25-34 |
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安全声明 (欧洲) | 16-26-36/37/39-45 |
危险品运输编码 | UN 3399 4.3/PG 1 |