13451-19-9

• 常用中文名：硝酸铽六水合物
• 常用英文名：terbium nitrate, hexahydrate
• CAS号：13451-19-9
• 分子式：H₁₂N₃O₁₅Tb
• 分子量：453.03200
• 相关类别： 无机化工 无机盐 金属硝酸盐及亚硝酸盐
• 发布时间：2018-05-09 08:00:00
• 更新时间：2024-01-05 16:11:36
• 下载msds

名称

• 中文名: 硝酸铽六水合物
• 英文名: terbium(3+),trinitrate,hexahydrate
• 中文别名: 硝酸鋱(III)六水
• 英文别名: Terbium trinitrate hexahydrate; EINECS 233-132-4; MFCD00149868

物化性质

• 沸点: 83ºC at 760 mmHg
• 熔点: 89.3 °C
• 分子式: H₁₂N₃O₁₅Tb
• 分子量: 453.03200
• 精确质量: 452.95200
• PSA: 262.02000
• LogP: 0.46650
• 外观性状: 白色 粉末 晶体
• 蒸汽压: 49.8mmHg at 25°C
• 储存条件:

  密闭于0-6 ºC阴凉干燥环境中

• 稳定性:

  遵照规定使用和储存则不会分解。

• 分子结构:

  1、摩尔折射率：无可用

  2、 摩尔体积（cm³/mol）：无可用

  3、 等张比容（90.2K）：无可用

  4、 表面张力（dyne/cm）：无可用

  5、 极化率：无可用

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:6

  3.氢键受体数量:15

  4.可旋转化学键数量:0

  5.互变异构体数量:无

  6.拓扑分子极性表面积195

  7.重原子数量:19

  8.表面电荷:0

  9.复杂度:18.8

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:10

• 更多:

  1. 性状：无可用

  2. 密度（g/mL,25/4℃）：无可用

  3. 相对蒸汽密度（g/mL,空气=1）：无可用

  4. 熔点（ºC）：89.3

  5. 沸点（ºC,常压）：无可用

  6. 沸点（ºC,5.2kPa）：无可用

  7. 折射率：无可用

  8. 闪点（ºC）：无可用

  9. 比旋光度（º）：无可用

  10. 自燃点或引燃温度（ºC）：无可用

  11. 蒸气压（kPa,25ºC）：无可用

  12. 饱和蒸气压（kPa,60ºC）：无可用

  13. 燃烧热（KJ/mol）：无可用

  14. 临界温度（ºC）：无可用

  15. 临界压力（KPa）：无可用

  16. 油水（辛醇/水）分配系数的对数值：无可用

  17. 爆炸上限（%,V/V）：无可用

  18. 爆炸下限（%,V/V）：无可用

  19. 溶解性：无可用

MSDS

Name: Terbium(iii)nitrate hexahydrate 99.9% Material Safety Data Sheet Synonym: Nitric acid, terbium (3+) salt texahydrat CAS: 13451-19-9 Section 1 - Chemical Product MSDS Name:Terbium(iii)nitrate hexahydrate 99.9% Material Safety Data Sheet Synonym:Nitric acid, terbium (3+) salt texahydrat Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 13451-19-9 TERBIUM(III)NITRATE HEXAHYDRATE 99.9 unlisted Hazard Symbols: O Risk Phrases: 8 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Contact with combustible material may cause fire.The toxicological properties of this material have not been fully investigated.Hygroscopic (absorbs moisture from the air). Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. Inhalation: Remove from exposure and move to fresh air immediately. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. Extinguishing Media: Use water only! Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Ground and bond containers when transferring material. Avoid contact with skin and eyes. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with clothing and other combustible materials. Avoid ingestion and inhalation. Use only in a chemical fume hood. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 13451-19-9: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: white Odor: Odorless pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 89.3 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: soluble in water Specific Gravity/Density: Molecular Formula: N3O9Tb.6H2O Molecular Weight: 453.02 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, combustible materials, exposure to moist air or water. Incompatibilities with Other Materials: Strong reducing agents, strong acids. Hazardous Decomposition Products: Nitrogen oxides. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 13451-19-9: WY9625000 LD50/LC50: CAS# 13451-19-9: Oral, rat: LD50 = >5 gm/kg. Carcinogenicity: TERBIUM(III)NITRATE HEXAHYDRATE - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: NITRATES, INORGANIC, N.O.S. Hazard Class: 5.1 UN Number: 1477 Packing Group: II IMO Shipping Name: NITRATES, INORGANIC, N.O.S. Hazard Class: 5.1 UN Number: 1477 Packing Group: II RID/ADR Shipping Name: NITRATES, INORGANIC, N.O.S. Hazard Class: 5.1 UN Number: 1477 Packing group: II Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: O Risk Phrases: R 8 Contact with combustible material may cause fire. Safety Phrases: S 17 Keep away from combustible material. WGK (Water Danger/Protection) CAS# 13451-19-9: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 13451-19-9 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 13451-19-9 is not on the TSCA Inventory because it is a hydrate. It is considered to be listed if the CAS number for the anhydrous form is on the inventory (40CFR720.3(u)(2)). SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。 CHEMICAL IDENTIFICATION RTECS NUMBER : WY9625000 CAS REGISTRY NUMBER : 13451-19-9 LAST UPDATED : 199203 DATA ITEMS CITED : 5 MOLECULAR FORMULA : N3-O9.Tb.6H2-O MOLECULAR WEIGHT : 453.07 WISWESSER LINE NOTATION : TB N-O3*3 &QH 6 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : >5 gm/kg TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) REFERENCE : TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 5,750,1963 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 260 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 5,750,1963 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 30 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 5,750,1963 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 480 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 5,750,1963 *** REVIEWS *** TOXICOLOGY REVIEW JPMSAE Journal of Pharmaceutical Sciences. (American Pharmaceutical Assoc., 2215 Constitution Ave., NW, Washington, DC 20037) V.50- 1961- Volume(issue)/page/year: 54,663,1965

安全

• 符号: GHS03, GHS07
• 信号词: Danger
• 危害声明: H272-H315-H319-H335
• 警示性声明: P220-P261-P305 + P351 + P338
• 个人防护装备: dust mask type N95 (US);Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
• 危害码 (欧洲): O: Oxidizing agent;Xi: Irritant;
• 风险声明 (欧洲): R8
• 安全声明 (欧洲): S17-S26-S36/37/39
• 危险品运输编码: UN 1477 5.1/PG 3
• WGK德国: 2
• RTECS号: WY9625000
• 包装等级: III
• 危险类别: 5.1