42014-60-8

• 常用中文名：4-叔丁基-2,6-二甲基-苯胺
• 常用英文名：4-tert-Butyl-2,6-dimethylaniline
• CAS号：42014-60-8
• 分子式：C₁₂H₁₉N
• 分子量：177.28600
• 发布时间：2018-03-16 08:00:00
• 更新时间：2024-01-09 12:55:30
• 下载msds

名称

• 中文名: 4-叔丁基-2,6-二甲基苯胺
• 英文名: 4-(tert-Butyl)-2,6-dimethylaniline
• 中文别名: 4-叔丁基-2,6-二甲基-苯胺
• 英文别名: 4-tert-butyl-2,6-dimethylaniline; MFCD00052181

物化性质

• 密度: 0.928g/cm3
• 沸点: 96ºC
• 分子式: C₁₂H₁₉N
• 分子量: 177.28600
• 闪点: 111.8ºC
• 精确质量: 177.15200
• PSA: 26.02000
• LogP: 3.76430
• 折射率: 1.525
• 储存条件: 2-8°C

MSDS

Name: 4-(tert-Butyl)-2 6-dimethylaniline Material Safety Data Sheet Synonym: CAS: 42014-60-8 Section 1 - Chemical Product MSDS Name:4-(tert-Butyl)-2 6-dimethylaniline Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 42014-60-8 2-Fluorophenylboronic Acid 95+% unlisted Hazard Symbols: XN Risk Phrases: 20/21/22 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Harmful if inhaled. Causes respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 42014-60-8: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: Colourless Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 90 deg C @0.3mm Hg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C12H19N Molecular Weight: 177.29 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, oxides of nitrogen, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 42014-60-8 unlisted. LD50/LC50: Not available. Carcinogenicity: 2-Fluorophenylboronic Acid - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.* Hazard Class: 6.1 UN Number: 2810 Packing Group: III IMO Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2810 Packing Group: III RID/ADR Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2810 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 23 Do not inhale gas/fumes/vapour/spray. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 42014-60-8: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 42014-60-8 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 42014-60-8 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi
• 风险声明 (欧洲): R20/21/22
• 安全声明 (欧洲): 26-36/37/39
• 危险品运输编码: 2810.0
• 海关编码: 2921430090

合成路线

6279-89-6 ~91% 42014-60-8

文献：Osuka, Atsuhiro; Shimizu, Hirohito; Suzuki, Hitomi Chemistry Letters, 1983 , p. 1373 - 1374

108-38-3 ~% 42014-60-8

文献：Yamato, Takehiko; Arimura, Takashi; Tashiro, Masashi Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1987 , p. 1 - 8

98-19-1 ~% 42014-60-8

文献：Small, Brooke L.; Rios, Ray; Fernandez, Eric R.; Gerlach, Deidra L.; Halfen, Jason A.; Carney, Michael J. Organometallics, 2010 , vol. 29, # 24 p. 6723 - 6731

上下游产品

上游产品  3
6279-89-6 108-38-3 98-19-1
下游产品  6
107342-55-2 443-88-9 879-97-0 88166-76-1
58280-58-3 5345-05-1

海关

海关编码	2921430090
中文概述	2921430090 甲苯胺及其衍生物以及它们的盐. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%
申报要素	品名, 成分含量, 用途, 原产地证据文件及编号(例 附原产地证书, 原产于欧盟的
Summary	HS:2921430090 toluidines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%