14995-22-3

• 常用中文名：异丙氧铁
• 常用英文名：Iron(III) isopropoxid
• CAS号：14995-22-3
• 分子式：C₉H₂₁FeO₃
• 分子量：233.10600
• 相关类别： 有机原料 有机金属类化合物 有机铁
• 发布时间：2018-08-09 15:08:33
• 更新时间：2024-01-13 17:10:53

名称

• 中文名: 异丙氧基铁(III)
• 英文名: iron(3+),propan-2-olate
• 中文别名: 异丙氧铁
• 英文别名: Ferric triisopropoxide; Ferricisopropoxide; Iron triisopropoxide; MFCD00070436

物化性质

• 密度: 0.79
• 沸点: 82℃
• 分子式: C₉H₂₁FeO₃
• 分子量: 233.10600
• 闪点: 12°(54°F)
• 精确质量: 233.08400
• PSA: 27.69000
• LogP: 2.62460
• 外观性状: solid | brown to black
• 储存条件:

  密闭于阴凉干燥环境中

• 稳定性:

  遵照规定使用和储存则不会分解。

• 水溶解性: It hydrolyzes with water.
• 分子结构:

  1、摩尔折射率：无可用

  2、 摩尔体积（cm³/mol）：无可用

  3、 等张比容（90.2K）：无可用

  4、 表面张力（dyne/cm）：无可用

  5、 极化率：无可用

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:3

  4.可旋转化学键数量:0

  5.互变异构体数量:无

  6.拓扑分子极性表面积69.2

  7.重原子数量:13

  8.表面电荷:0

  9.复杂度:10.8

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:4

• 更多:

  1. 性状：无可用

  2. 密度（g/mL,25/4℃）：无可用

  3. 相对蒸汽密度（g/mL,空气=1）：无可用

  4. 熔点（ºC）：无可用

  5. 沸点（ºC,常压）：无可用

  6. 沸点（ºC,5.2kPa）：无可用

  7. 折射率：无可用

  8. 闪点（ºC）：无可用

  9. 比旋光度（º）：无可用

  10. 自燃点或引燃温度（ºC）：无可用

  11. 蒸气压（kPa,25ºC）：无可用

  12. 饱和蒸气压（kPa,60ºC）：无可用

  13. 燃烧热（KJ/mol）：无可用

  14. 临界温度（ºC）：无可用

  15. 临界压力（KPa）：无可用

  16. 油水（辛醇/水）分配系数的对数值：无可用

  17. 爆炸上限（%,V/V）：无可用

  18. 爆炸下限（%,V/V）：无可用

  19. 溶解性：无可用

MSDS

Section 1: Product Identification Chemical Name:Iron (III) i-propoxide (99.9+%-Fe) CAS Registry Number:14995-22-3 Formula:Fe(OC3H7)3 EINECS Number:None Chemical Family:metal alkoxide Synonym:Ferric propoxide, Iron propylate Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound14995-22-3100%1 mg/m3 (Sol Fe)no data Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and respiratory tract. Primary Routes of Exposure:Ingestion, skin, inhalation, eyes Eye Contact:Causes slight to mild irritation of the eyes. Skin Contact:Causes irritation, redness, and pain to skin. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. Ingestion:No information on the physiological effects of ingestion. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Prolonged ingestion may lead to damage to the liver and pancreas. Prolonged inhalation of dusts may cause Chronic Health Affects: pulmonary fibrosis. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:53°F(2-propanol) Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, water, foam or dry powder If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self- contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit irritating fumes. Decomposion Products: Unusual Fire or Explosion Hazards: Contact with moisture will produce flammable isopropanol SECTION 6: Accidental Release Measures Remove sources of ignition. Small spills can be mixed with vermiculite, sodium carbonate or other suitable non Spill and Leak Procedures: combustible adsorbent and swept up. SECTION 7: Handling and Storage Keep material in a tightly sealed container in a cool dry place. Prolonged exposure to the moist air will result in Handling and Storage: degradation of the product. Handle and store material under a dry atmosphere. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:brown to black solid Molecular Weight:233.12 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:slight alcohol odor Solubility in Water:hydrolyzes in water SECTION 10: Stability and Reactivity Stability:moisture sensitive Hazardous Polymerization:no hazardous polymerization Prolonged contact with air or moisture. Keep away from heat and ignition sources including open flame and Conditions to Avoid: electrostatic discharge. Incompatibility:Oxidizing agents, halogens and active metals Decomposition Products:carbon dioxide, carbon monoxide, organic fumes, and iron oxide SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data Mutagenic Effects:No data Tetratogenic Effects:No data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:None SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。

安全

• 危害码 (欧洲): F+
• 危险品运输编码: UN3180
• 包装等级: III
• 危险类别: 4.1