206060-42-6

• 常用中文名：Fmoc-L-3-硝基苯丙氨酸
• 常用英文名：Fmoc-D-phe(3-NO2)-OH
• CAS号：206060-42-6
• 分子式：C₂₄H₂₀N₂O₆
• 分子量：432.425
• 发布时间：2018-12-02 19:32:53
• 更新时间：2024-01-03 13:20:19

名称

• 中文名: N-[(9H-芴-9-基甲氧基)羰基]-3-硝基-L-苯丙氨酸
• 英文名: 2-(9H-fluoren-9-ylmethoxycarbonylamino)-3-(3-nitrophenyl)propanoic acid
• 英文别名: MFCD01631072; Fmoc-3-Nitro-L-phenylalanine; 3-Nitro-D-phenylalanine,N-FMOC protected; N-[(9H-Fluoren-9-ylmethoxy)carbonyl]-3-nitro-L-phenylalanine; Fmoc-D-phe(3-NO2)-OH; L-Phenylalanine, N-[(9H-fluoren-9-ylmethoxy)carbonyl]-3-nitro-; 3-Nitro-L-phenylalanine,N-FMOC protected; FMOC-L-3-NITROPHENYLALANINE

物化性质

• 密度: 1.4±0.1 g/cm3
• 沸点: 690.1±55.0 °C at 760 mmHg
• 熔点: 140ºC
• 分子式: C₂₄H₂₀N₂O₆
• 分子量: 432.425
• 闪点: 371.1±31.5 °C
• 精确质量: 432.132141
• PSA: 121.45000
• LogP: 5.14
• 蒸汽压: 0.0±2.3 mmHg at 25°C
• 折射率: 1.650
• 储存条件: Store at R.T.

MSDS

Name: (S)-N-FMOC-3-Amino-3-(3-Nitrophenyl)Propanoic Acid 95% (98% E.E.) Material Safety Data Sheet Synonym: (S)-N-(9-Fluorenylmethoxycarbonyl)-3-Amino-(3-Nitrophenyl)Propionic Acid; (S)-N-FMOC-beta-(3-Nitrophenyl)-beta-Alanine CAS: 206060-42-6 Section 1 - Chemical Product MSDS Name:(S)-N-FMOC-3-Amino-3-(3-Nitrophenyl)Propanoic Acid 95% (98% E.E.) Material Safety Data Sheet Synonym:(S)-N-(9-Fluorenylmethoxycarbonyl)-3-Amino-(3-Nitrophenyl)Propionic Acid; (S)-N-FMOC-beta-(3-Nitrophenyl)-beta-Alanine Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 206060-42-6 (S)-N-FMOC-3-Amino-3-(3-Nitrophenyl)Pr 95% unlisted Hazard Symbols: None Listed. Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 206060-42-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: white to off-white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 140 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Not available. Solubility in water: Specific Gravity/Density: Molecular Formula: C24H20N2O6 Molecular Weight: 432.44 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions. Conditions to Avoid: Incompatible materials, dust generation. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 206060-42-6 unlisted. LD50/LC50: Not available. Carcinogenicity: (S)-N-FMOC-3-Amino-3-(3-Nitrophenyl)Propanoic Acid. - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 206060-42-6: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 206060-42-6 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 206060-42-6 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi
• 安全声明 (欧洲): S24/25
• 海关编码: 2924299090

海关

海关编码	2924299090
中文概述	2924299090. 其他环酰胺（包括环氨基甲酸酯）（包括其衍生物以及他们的盐）. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
申报要素	品名, 成分含量, 用途, 包装
Summary	2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%