68553-60-6

• 常用中文名：环烷酸氧化钒
• 常用英文名：vanadium naphthenate oxide
• CAS号：68553-60-6
• 分子式：C₄₄H₂₈O₈V
• 分子量：735.63000
• 相关类别： 有机原料 羧酸类化合物及衍生物 羧酸酯及其衍生物的盐
• 发布时间：2018-09-18 19:26:45
• 更新时间：2024-01-12 12:21:22

名称

• 中文名: 环烷酸氧化钒
• 英文名: Vanadium Naphthenate Oxide in Naphthenic Acid
• 中文别名: 萘酸氧化钒
• 英文别名: EINECS 271-395-7; MFCD00148763; naphthalene-2-carboxylate,vanadium(4+)

物化性质

• 密度: 1.04 g/cm3
• 分子式: C₄₄H₂₈O₈V
• 分子量: 735.63000
• 闪点: 30ºC
• 精确质量: 735.12200
• PSA: 160.52000
• LogP: 4.81320
• 外观性状: 绿色油性液体
• 储存条件:

  存放在密封容器内，并放在阴凉，干燥处。储存的地方必须上锁，钥匙必须交给技术专家和他们的助手保管。储存的地方必须远离氧化剂。

• 稳定性:

  远离氧化物。

• 水溶解性: Insoluble in water.
• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:8

  4.可旋转化学键数量:0

  5.互变异构体数量:无

  6.拓扑分子极性表面积161

  7.重原子数量:53

  8.表面电荷:0

  9.复杂度:195

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:5

• 更多:

  1. 性状：黑色液体。

  2. 密度（g/mL,25/4℃）：1.04

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：未确定

  5. 沸点（ºC,常压）：未确定

  6. 沸点（ºC,5.2kPa）：未确定

  7. 折射率：未确定

  8. 闪点（ºC）：未确定

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：＞350

  11. 蒸气压（kPa,25ºC）：未确定

  12. 饱和蒸气压（kPa,60ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：不能溶于水。

MSDS

Section 1: Product Identification Chemical Name:Vanadyl naphthenate, 35% in naphthenic acid (2.8-3.2% V) CAS Registry Number:68553-60-6 Formula:Vanadyl salt of napthenic acid EINECS Number:none Chemical Family:metal carboxylate Synonym:Naphthenic acid, vanadium salt, in alkylated cycloalkane carboxylic acids. Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound68553-60-635%no datano data naphthenic acid1338-24-565%no datano data Section 3: Hazards Identification Emergency Overview:Severely irritating to eyes, skin and respiratory tract. May be harmful if swallowed. Primary Routes of Exposure:Ingestion, eyes, inhalation, skin Eye Contact:Causes severe irritation to the eyes. Skin Contact:Causes moderate to severe irritation of the skin. Inhalation:Vapor will severely irritate the nose, mucous membranes and respiratory tract. Ingestion:Ingestion may cause gastrointestinal distress, nausea, dizziness, weakness. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical Skin Exposure: assistance if irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Ingestion:Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). SECTION 5: Fire Fighting Measures Flash Point:>350 °F Autoignition Temperature:no data Explosion Limits:none Extinguishing Medium:carbon dioxide, dry powder or foam If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained Special Fire Fighting Procedures: breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Eliminate all ignition sources. Small spills may be adsorbed into diatomaceous earth, sand, or other suitable Spill and Leak Procedures: adsorbent, and swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a sealed container. Keep away from heat and moisture. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear appropriate chemical resistant gloves and protective clothing. Ventilation:Material may form a vapor. If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a vapor. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:viscous liq. Molecular Weight:not applicable Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:1.04 Odor:organic odor Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable liquid Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:oxidizing agents, bases Decomposition Products:Carbon dioxide, carbon monoxide, organic vapors, and metal oxides and carbonates. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files for title compound. Naphthenic acid: Oral (rat) LD50: 3g/Kg; Carcinogenic Effects:none Mutagenic Effects:none Tetratogenic Effects:none SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:Not listed in the TSCA inventory SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 对水稍微有危害的，不要让未稀释或者大量产品接触地下水，水道或者污水系统。若无政府许可，勿将材料排入周围环境。

安全

• 风险声明 (欧洲): R36/37/38
• 安全声明 (欧洲): S26-S36-S37-S39
• 危险品运输编码: UN 3285 6.1/PG 3
• 包装等级: III
• 危险类别: 6.1