Chloro{2,6-bis[(phenylseleno-Se)methyl]phenyl-C}palladium(II)结构式
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常用名 | Chloro{2,6-bis[(phenylseleno-Se)methyl]phenyl-C}palladium(II) | 英文名 | Chloro{2,6-bis[(phenylseleno-Se)methyl]phenyl-C}palladium(II) |
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CAS号 | 761459-93-2 | 分子量 | 559.18 | |
密度 | N/A | 沸点 | N/A | |
分子式 | C20H19ClPdSe2 | 熔点 | 162-221°C | |
MSDS | 美版 | 闪点 | N/A | |
符号 |
GHS06, GHS08 |
信号词 | Danger |
英文名 | Chloro{2,6-bis[(phenylseleno-Se)methyl]phenyl-C}palladium(II) |
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熔点 | 162-221°C |
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分子式 | C20H19ClPdSe2 |
分子量 | 559.18 |
储存条件 | 2-8°C |
符号 |
GHS06, GHS08 |
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信号词 | Danger |
危害声明 | H301 + H311 + H331-H351 |
警示性声明 | P261-P280-P301 + P310-P311 |
危害码 (欧洲) | T |
风险声明 (欧洲) | 23/24/25-40 |
安全声明 (欧洲) | 36/37-45 |
危险品运输编码 | UN 3283 6.1 / PGIII |
WGK德国 | 3 |
Petasis Borono-Mannich reaction and allylation of carbonyl compounds via transient allyl boronates generated by palladium-catalyzed substitution of allyl alcohols. an efficient one-pot route to stereodefined alpha-amino acids and homoallyl alcohols.
J. Am. Chem. Soc. 129 , 13723 - 13731, (2007) An efficient one-pot procedure was designed by integration of the pincer-complex-catalyzed borylation of allyl alcohols in the Petasis borono-Mannich reaction and in allylation of aldehydes and ketone... |