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One-Dimensional Hetero-Nanostructures for Rechargeable Batteries
10.1021/acs.accounts.8b00031 2018-04-05 This Account summarizes fabrication strategies for 1D hetero-nanostructures, including nucleation and growth, deposition, and melt-casting and electrospinning. Besides, the chemical principles for each strategy are discussed. The nucleation and growth strateg... |
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Protein–Protein Interactions in the Molecular Chaperone Network
10.1021/acs.accounts.8b00036 2018-04-03 This Account will discuss the efforts of our group and others to map, measure, and chemically perturb the PPIs within the molecular chaperone network. Structural biology methods, including X-ray crystallography, NMR spectroscopy, and electron microscopy, have... |
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Unimolecular Decay of Criegee Intermediates to OH Radical Products: Prompt and Thermal Decay Processes
10.1021/acs.accounts.8b00077 2018-04-03 The dimethyl-substituted Criegee intermediate, (CH3)2COO, is utilized in this Account to showcase recent efforts to experimentally measure and theoretically predict the rates for prompt and thermal unimolecular decay processes of prototypical Criegee intermed... |
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Molecular Clusters: Nanoscale Building Blocks for Solid-State Materials
10.1021/acs.accounts.8b00016 2018-03-31 Superatomic crystals have proven to be both robust and tunable, representing a new method of materials design and architecture. This Account demonstrates how precisely controlling the structure and properties of nanoscale building blocks is key in developing ... |
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In Situ Cellular Glycan Analysis
10.1021/acs.accounts.7b00617 2018-03-29 Glycan decorates all mammalian cell surfaces through glycosylation, which is one of the most important post-modifications of proteins. Glycans mediate a wide variety of biological processes, including cell growth and differentiation, cell–cell communication, ... |
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Orotidine 5′-Monophosphate Decarboxylase: Probing the Limits of the Possible for Enzyme Catalysis
10.1021/acs.accounts.8b00059 2018-03-29 The mystery associated with catalysis by what were once regarded as protein black boxes, diminished with the X-ray crystallographic determination of the three-dimensional structures of enzyme–substrate complexes. The report that several high-resolution X-ray ... |
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Tailoring Interfacial Nanoparticle Organization through Entropy
10.1021/acs.accounts.8b00001 2018-03-28 In summary, entropy strategies offer a promising and abundant framework for precisely programming the structural organization of NPs at interfaces. We discuss future directions to signify the framework in tailoring the interfacial organization of NPs. We hope... |
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Magnetic Nanotweezers for Interrogating Biological Processes in Space and Time
10.1021/acs.accounts.8b00004 2018-03-28 MNTs have the potential to be utilized in many exciting applications across diverse biological systems spanning from fundamental biology investigations of spatial and mechanical signaling dynamics at the single-cell and systems levels to in vivo therapeutic a... |
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Designing Helical Molecular Capsules Based on Folded Aromatic Amide Oligomers
10.1021/acs.accounts.8b00075 2018-03-28 The ab initio rational structure-based design of a synthetic molecular receptor for a given complex biomolecular guest remains an elusive objective, yet remarkable progress has been achieved in recent years. This Account deals with the use of folded artificia... |
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Electrolytic CO2 Reduction in a Flow Cell
10.1021/acs.accounts.8b00010 2018-03-23 In this Account, we examine some of the systems-level strategies that have been applied in an effort to tailor flow reactor components to improve electrocatalytic reduction. Flow reactors that have been utilized in CO2 electrolysis schemes can be categorized ... |