Phosphazene base-catalyzed condensation of trimethylsilylacetate with carbonyl compounds.
Koji Kobayashi, Masahiro Ueno, Yoshinori Kondo
Index: Chem. Commun. (Camb.) (29) , 3128-30, (2006)
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Abstract
The t-Bu-P4 base was found to be an excellent catalyst for the condensation of trimethylsilylacetate or trimethylacetonitrile with carbonyl compounds to form functionalized alkenes and beta-enaminoesters were also synthesized by the condensation with formanilides.
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