Stannylated allyl carbonates as versatile building blocks for the diversity oriented synthesis of allylic amines and amides.
Christian Bukovec, Uli Kazmaier
Index: Org. Biomol. Chem. 9 , 2743-2750, (2011)
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Abstract
Stannylated allylic carbonates are suitable substrates for Pd-catalyzed allylic aminations. In DMF and with [allylPdCl](2) as catalyst the stannylated allyl amines formed can be directly coupled with electrophiles according to the Stille protocol, giving rise to highly functionalized building blocks in excellent yields.
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