A method for synthesis of homoallylic bromide.
Wenke Qi, Peipei Wang, Liyuan Fan, Songlin Zhang
Index: J. Org. Chem. 78(12) , 5918-24, (2013)
Full Text: HTML
Abstract
Cyclopropyl Grignard reagents react with carbonyl compounds in the presence of diethyl phosphite to give homoallylic bromides. The reaction is effectively carried out under mild conditions in a one-pot fashion with moderate to good yields.
Related Compounds
Related Articles:
Silver-catalyzed radical phosphonofluorination of unactivated alkenes.
2013-09-25
[J. Am. Chem. Soc. 135(38) , 14082-5, (2013)]
2005-10-27
[Org. Lett. 7(22) , 4871-4, (2005)]
Synthesis and antiproliferative activity of novel α-aminophosphonates.
2012-01-01
[Chem. Pharm. Bull. 60(12) , 1531-7, (2012)]
2013-06-01
[J. Am. Soc. Mass Spectrom. 24(6) , 917-25, (2013)]