N-Methylcyclohexanamine

Names

[ CAS No. ]:
100-60-7

[ Name ]:
N-Methylcyclohexanamine

[Synonym ]:
L6TJ AM1
N-Methylcyclohexanamine
MFCD00003832
N-Cyclohexylmethylamine
Cyclohexanamine, N-methyl-
N-Methylcyclohexylamine
EINECS 202-869-3

Chemical & Physical Properties

[ Density]:
0.8±0.1 g/cm3

[ Boiling Point ]:
146.5±8.0 °C at 760 mmHg

[ Melting Point ]:
−9-−7 °C(lit.)

[ Molecular Formula ]:
C₇H₁₅N

[ Molecular Weight ]:
113.201

[ Flash Point ]:
29.4±0.0 °C

[ Exact Mass ]:
113.120445

[ PSA ]:
12.03000

[ LogP ]:
1.63

[ Vapour density ]:
4 (vs air)

[ Vapour Pressure ]:
4.6±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.451

[ Storage condition ]:
Flammables area

[ Water Solubility ]:
5.4 g/100 mL (20 ºC)

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: GX1529000

CHEMICAL NAME :: Cyclohexylamine, N-methyl-

CAS REGISTRY NUMBER :: 100-60-7

BEILSTEIN REFERENCE NO. :: 1523664

LAST UPDATED :: 199709

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C7-H15-N

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 400 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - tremor Behavioral - ataxia

REFERENCE :: 34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969 Volume(issue)/page/year: -,388,1969

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 2 gm/kg

TOXIC EFFECTS :: Skin and Appendages - corrosive (after topical exposure)

REFERENCE :: 34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969 Volume(issue)/page/year: -,388,1969

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 7000 mg/m3/1H

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - lacrimation Behavioral - convulsions or effect on seizure threshold Lungs, Thorax, or Respiration - dyspnea

REFERENCE :: 34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969 Volume(issue)/page/year: -,388,1969 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X1402 No. of Facilities: 426 (estimated) No. of Industries: 5 No. of Occupations: 6 No. of Employees: 4190 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H302 + H312-H314-H331

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive

[ Risk Phrases ]:
R10;R20/21/22;R35

[ Safety Phrases ]:
S16-S26-S36/37/39-S45

[ RIDADR ]:
UN 2734 8/PG 2

[ WGK Germany ]:
1

[ RTECS ]:
GX1529000

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
29213099

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2921300090

[ Summary ]:
2921300090 other cyclanic, cyclenic or cyclotherpenic mono- or polyamines, and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Corrosion inhibition of carbon steel in petroleum/water mixtures by N-containing compounds. Ashassi-Sorkhabi H and Nabavi-Amri AS.

Acta Chim. Slov. 47(4) , 507-518, (2000)

Ultrasonic Velocity, Viscosity, Density and Excess Properties of Ternary Mixture of N-Methylcyclohexylamine+ Benzene+ 1-Propanol. Vasantharani P, et al.

Asian J. Applied Sciences 2(2) , 169-176, (2009)