Cloprop

Names

[ CAS No. ]:
101-10-0

[ Name ]:
Cloprop

[Synonym ]:
2-(3-Chlorophenoxy)propionic Acid
MFCD00009723
Propanoic acid, 2-(3-chlorophenoxy)-
Cloprop
rac-(2R)-2-(3-chlorophenoxy)propanoic acid
DL-2-(m-Chlorophenoxy)Propionic Acid
2-(3-Chlorophenoxy)propanoic acid
2-(3-Chlorophenoxy)-propionic acid
(RS)-2-(3-chlorophenoxy)propionic acid
EINECS 202-915-2

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
318.5±17.0 °C at 760 mmHg

[ Melting Point ]:
113-115 °C(lit.)

[ Molecular Formula ]:
C₉H₉ClO₃

[ Molecular Weight ]:
200.619

[ Flash Point ]:
146.4±20.9 °C

[ Exact Mass ]:
200.024017

[ PSA ]:
46.53000

[ LogP ]:
2.52

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.547

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: UE9285000

CHEMICAL NAME :: Propionic acid, 2-(m-chlorophenoxy)-

CAS REGISTRY NUMBER :: 101-10-0

BEILSTEIN REFERENCE NO. :: 1876444

LAST UPDATED :: 199701

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C9-H9-Cl-O3

MOLECULAR WEIGHT :: 200.63

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >750 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C147,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >2 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,180,1991 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
2

[ RTECS ]:
UE9285000

[ Hazard Class ]:
3.2

[ HS Code ]:
2918990028

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2918990028

Articles

Enantiomeric separation of chiral phenoxy acid herbicides by electrokinetic chromatography. Application to the determination of analyte-selector apparent binding constants for enantiomers.

Electrophoresis 22(15) , 3216-25, (2001)

The enantiomeric resolution of chiral phenoxy acid herbicides was performed by electrokinetic chromatography using a cyclodextrin as chiral pseudophase (CD-EKC). A systematic evaluation of several neu...