2-Benzylidene-1-heptanol

Names

[ CAS No. ]:
101-85-9

[ Name ]:
2-Benzylidene-1-heptanol

[Synonym ]:
1-Heptanol, 2-(phenylmethylene)-
2-Benzylidene-1-heptanol
2-Benzylideneheptan-1-ol
Amylcinnamyl alcohol
α-Amylcinnamyl alcohol
EINECS 202-982-8
MFCD00022004
alpha-Amylcinnamic alcohol

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
331.3±11.0 °C at 760 mmHg

[ Molecular Formula ]:
C₁₄H₂₀O

[ Molecular Weight ]:
204.308

[ Flash Point ]:
134.1±15.1 °C

[ Exact Mass ]:
204.151413

[ PSA ]:
20.23000

[ LogP ]:
4.37

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.547

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: MJ3280000

CHEMICAL NAME :: 1-Heptanol, 2-benzylidene-

CAS REGISTRY NUMBER :: 101-85-9

BEILSTEIN REFERENCE NO. :: 3127316

LAST UPDATED :: 199709

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C14-H20-O

MOLECULAR WEIGHT :: 204.34

WISWESSER LINE NOTATION :: Q1Y5&U1R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 4 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 12,817,1974

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 12,817,1974 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X1715 No. of Facilities: 48 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 96 (estimated)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H319

[ Precautionary Statements ]:
P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
36

[ Safety Phrases ]:
S26;S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
2

[ RTECS ]:
MJ3280000

[ HS Code ]:
2906299090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2906299090

[ Summary ]:
2906299090 other aromatic alcohols。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

Sensitivity to alpha-amylcinnamic aldehyde and alpha-amylcinnamic alcohol.

J. Am. Acad. Dermatol. 8(1) , 76-80, (1983)

Sensitivity to alpha-amylcinnamic aldehyde (alpha-AcAld) is apparently uncommon, but, like allergy to alpha-amylcinnamic alcohol (alpha-AcAlc), it often accompanies allergy to the perfume in Mycolog c...

Formaldehyde generators: relationship between stability, lipophilicity and carcinogenic potency.

Carcinogenesis 3(11) , 1273-6, (1982)

The rate of hydrolysis to formaldehyde of methylenedimorpholine (MDM), hexamethylenetetramine (HMT) and dinitrosopentamethylenetetramine (DNPT) have been compared with the enzyme-mediated formation of...

Fragrance material review on alpha-amylcinnamyl alcohol.

Food Chem. Toxicol. 45 Suppl 1 , S32-9, (2007)

A toxicologic and dermatologic review of alpha-amylcinnamyl alcohol when used as a fragrance ingredient is presented.