N,N'-Bis(1-methylpropyl)-1,4-phenylenediamine
Names
[ CAS No. ]:
101-96-2
[ Name ]:
N,N'-Bis(1-methylpropyl)-1,4-phenylenediamine
[Synonym ]:
N,N'-Di-sec-butyl-p-phenylenediamine
N,N′-Di-sec-butyl-p-phenylenediamine
1,4-Benzenediamine, N,N-bis(1-methylpropyl)-
N,N'-Di(butan-2-yl)benzene-1,4-diamine
EINECS 202-992-2
NN'-Di-sec-butyl-p-phenylenediamine
N,N'-bis(1-methylpropyl)benzene-1,4-diamine
N,N'-Di-sec-butyl-1,4-benzenediamine
N,N'-Di-sec-butylbenzene-1,4-diamine
NN'-Bis(1-methylpropyl)-1,4-phenylenediamine
MFCD00043658
2Y1&MR DMY2&1
N,N'-Bis(1-methylpropyl)-1,4-phenylenediamine
N,N'-Di-sec-butyl-1,4-phenylenediamine
Chemical & Physical Properties
[ Density]:
0.942
[ Boiling Point ]:
343.2±25.0 °C at 760 mmHg
[ Melting Point ]:
17.8°C
[ Molecular Formula ]:
C14H24N2
[ Molecular Weight ]:
220.354
[ Flash Point ]:
192.6±14.9 °C
[ Exact Mass ]:
220.193954
[ PSA ]:
24.06000
[ LogP ]:
3.39
[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C
[ Index of Refraction ]:
1.539
[ Stability ]:
正常温度和压力下稳定
[ Water Solubility ]:
<0.1 g/100 mL at 20 ºC
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- SS9040000
- CHEMICAL NAME :
- p-Phenylenediamine, N,N'-di-sec-butyl-
- CAS REGISTRY NUMBER :
- 101-96-2
- BEILSTEIN REFERENCE NO. :
- 2805827
- LAST UPDATED :
- 199801
- DATA ITEMS CITED :
- 10
- MOLECULAR FORMULA :
- C14-H24-N2
- MOLECULAR WEIGHT :
- 220.40
- WISWESSER LINE NOTATION :
- 2Y1&MR DMY2&1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0555010
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration into the eye
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0555010 ** ACUTE TOXICITY DATA **
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 148 mg/kg
- TOXIC EFFECTS :
- Behavioral - somnolence (general depressed activity) Gastrointestinal - other changes Kidney, Ureter, Bladder - other changes in urine composition
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0555010
- TYPE OF TEST :
- LCLo - Lowest published lethal concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 600 mg/m3/6H
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- KODAK* Kodak Company Reports. (343 State St., Rochester, NY 14650) Volume(issue)/page/year: 21MAY1971
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 2806 mg/kg
- TOXIC EFFECTS :
- Behavioral - tremor Kidney, Ureter, Bladder - other changes in urine composition Skin and Appendages - dermatitis, other (after systemic exposure)
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0555010
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - guinea pig
- DOSE/DURATION :
- 5 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- RCTEA4 Rubber Chemistry and Technology. (American Chemical Soc., Rubber Division, c/o Mrs. M.E. Bauer, Univ. of Akron, Akron, OH 44325) V.1- 1928- Volume(issue)/page/year: 45,627,1972
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Mammal - species unspecified
- DOSE/DURATION :
- 10 mL/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- IPSTB3 International Polymer Science and Technology. (Rapra Technology Ltd., Shawbury, Shrewsbury, Shropshire SY4 4NR, UK) Volume(issue)/page/year: 3,93,1976 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X6950 No. of Facilities: 184 (estimated) No. of Industries: 3 No. of Occupations: 11 No. of Employees: 9196 (estimated) No. of Female Employees: 257 (estimated)
Safety Information
[ Symbol ]:
GHS05, GHS06, GHS09
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H301-H315-H317-H318-H410
[ Precautionary Statements ]:
P273-P280-P301 + P310 + P330-P305 + P351 + P338 + P310-P333 + P313
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
C:Corrosive
[ Risk Phrases ]:
R25;R34;R43;R50/53
[ Safety Phrases ]:
S26-S36/37/39-S45-S61
[ RIDADR ]:
UN 2922 8/PG 2
[ WGK Germany ]:
3
[ RTECS ]:
SS9040000
[ Packaging Group ]:
III
[ Hazard Class ]:
第8.2类碱性腐蚀品(国内暂不属于危险化学品范畴)
[ HS Code ]:
2921519090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2921519090
[ Summary ]:
2921519090. o-, m-, p-phenylenediamine, diaminotoluenes, and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:17.0%. . MFN tariff:6.5%. General tariff:30.0%