1,1'-(azodicarbonyl)-dipiperidine

Names

[ Name ]:
1,1'-(azodicarbonyl)-dipiperidine

[Synonym ]:
Piperidine, 1,1'-[azobis(carbonyl)]bis-
(E)-diazene-1,2-diylbis(piperidin-1-ylmethanone)
1,1'-Azobis(N,N-pentamethyleneformamide)
1,1-(Azodicarbonyl)-Dipiperidine
1,1'-(azodicarbonyl)-dipiperidine
MFCD00010111
(E)-1,2-Diazenediylbis(1-piperidinylmethanone)
Methanone, 1,1'-[(E)-1,2-diazenediyl]bis[1-(1-piperidinyl)-
Piperidine, 1,1'-(azodicarbonyl)bis-
Diazene-1,2-diylbis(piperidin-1-ylmethanone)
(NE)-N-(piperidine-1-carbonylimino)piperidine-1-carboxamide
1,1'-(Azodicarbonyl)dipiperidine
Azodicarboxylic acid dipiperidide

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
366.4±25.0 °C at 760 mmHg

[ Melting Point ]:
132-136 °C(lit.)

[ Molecular Formula ]:
C₁₂H₂₀N₄O₂

[ Molecular Weight ]:
252.313

[ Flash Point ]:
175.4±23.2 °C

[ Exact Mass ]:
252.158630

[ PSA ]:
65.34000

[ LogP ]:
0.99

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.622

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2933399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Copper salt catalyzed addition of arylboronic acids to azodicarboxylates.

J. Org. Chem. 70 , 8631, (2005)

The addition of arylboronic acids 1 to azodicarboxylates 2 in the presence of a catalytic amount of a copper salt under mild reaction conditions gives aryl-substituted hydrazines 3 in high yields. The...

Structure--activity relationships of 1beta-methyl-2-(5-phenylpyrrolidin-3-ylthio)carbapenems.

Bioorg. Med. Chem. 10 , 1595, (2002)

Structure--activity relationship studies of 1beta-methyl-2-[(3S,5R)-5-(4-aminomethylphenyl)pyrrolidin-3-ylthio]carbapenems, especially those pertaining to the relationship between antibacterial activi...

Radiosensitization, thiol oxidation, and inhibition of DNA repair by SR 4077.

Radiat. Res. 113 , 346, (1988)

The mechanism of radiosensitization by diazenedicarboxylic acid bis(N),N-piperidide (SR 4077), a less toxic analog of diamide, was studied using Chinese hamster ovary cells. SR 4077 gave an average SE...