n-Butane
Names
Chemical & Physical Properties
[ Density]:
0.87721 g/cm3 (20 ºC)
[ Boiling Point ]:
272.65 ºC
[ Melting Point ]:
220-221 ºC
[ Molecular Formula ]:
C4H10
[ Molecular Weight ]:
58.122
[ Flash Point ]:
-70.9±6.6 ºC
[ Exact Mass ]:
58.078251
[ LogP ]:
2.88
[ Vapour density ]:
2.11 (vs air)
[ Vapour Pressure ]:
1918.2±0.0 mmHg at 25°C
[ Index of Refraction ]:
1.46218 (589.3 nm 20 ºC)
[ Stability ]:
Stable. Extremely flammable. Readily forms explosive mixtures with air. Note low flash point. Incompatible with strong oxidizing agents, strong acids, strong alkalies.
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- EJ4200000
- CHEMICAL NAME :
- Butane
- CAS REGISTRY NUMBER :
- 106-97-8
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 26
- MOLECULAR FORMULA :
- C4-H10
- MOLECULAR WEIGHT :
- 58.14
- WISWESSER LINE NOTATION :
- 4H
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 658 gm/m3/4H
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- FATOAO Farmakologiya i Toksikologiya (Moscow). For English translation, see PHTXA6 and RPTOAN. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.2- 1939- Volume(issue)/page/year: 30,102,1967
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 680 gm/m3/2H
- REFERENCE :
- FATOAO Farmakologiya i Toksikologiya (Moscow). For English translation, see PHTXA6 and RPTOAN. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.2- 1939- Volume(issue)/page/year: 30,102,1967 *** REVIEWS *** ACGIH TLV-TWA 1900 mg/m3 (800 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 500 ppm (1200 mg/m3) DTLWS* "Documentation of the Threshold Limit Values for Substances in Workroom Air," Supplements. For publisher information, see 85INA8. Volume(issue)/page/year: 3,12,1973 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 800 ppm (1900 mg/m3) JAN 1993 OEL-AUSTRIA:TWA 1000 ppm (2300 mg/m3) (all isomers) JAN 1993 OEL-BELGIUM:TWA 800 ppm (1900 mg/m3) JAN 1993 OEL-DENMARK:TWA 500 ppm (1200 mg/m3) JAN 1993 OEL-FINLAND:TWA 800 ppm (1900 mg/m3);STEL 1000 ppm (2350 mg/m3) JAN 1993 OEL-FRANCE:TWA 800 ppm (1900 mg/m3) JAN 1993 OEL-GERMANY:TWA 1000 ppm (2350 mg/m3) (all isomers) JAN 1993 OEL-HUNGARY:TWA 300 mg/m3;STEL 900 mg/m3 JAN 1993 OEL-INDIA:TWA 800 ppm (1900 mg/m3) JAN 1993 OEL-JAPAN:TWA 500 ppm (1200 mg/m3) JAN 1993 OEL-THE NETHERLANDS:TWA 600 ppm (1430 mg/m3) JAN 1993 OEL-RUSSIA:TWA 500 ppm;STEL 300 mg/m3 JAN 1993 OEL-SWITZERLAND:TWA 800 ppm (1900 mg/m3) (all isomers) JAN 1993 OEL-UNITED KINGDOM:TWA 600 ppm (1430 mg/m3);STEL 750 ppm JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO BUTANE-air:10H TWA 800 ppm REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 13480 No. of Facilities: 5871 (estimated) No. of Industries: 55 No. of Occupations: 53 No. of Employees: 61958 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 13480 No. of Facilities: 69613 (estimated) No. of Industries: 307 No. of Occupations: 200 No. of Employees: 988880 (estimated) No. of Female Employees: 186786 (estimated)
Safety Information
[ Hazard Codes ]:
F+,F
[ Risk Phrases ]:
R12
[ Safety Phrases ]:
S9-S16
[ RIDADR ]:
UN 2037 2.1
[ WGK Germany ]:
-
[ RTECS ]:
EJ4200000
[ Hazard Class ]:
2.1
[ HS Code ]:
3606100000
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2901100000
[ Summary ]:
2901100000 saturated acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%