3-Mesityl-5,6,7,8-tetrahydro-4H-cyclohepta[d]thiazol-3-ium perchlorate

[ Molecular Formula ]:
C₁₇H₂₂ClNO₄S

[ Molecular Weight ]:
371.87900

[ Exact Mass ]:
371.09600

[ PSA ]:
106.39000

[ LogP ]:
4.43320

Click to get detail MSDS

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Hazard Codes ]:
Xi

[ RIDADR ]:
NONH for all modes of transport

Click to get detail synthetic route

Precursor

DownStream

Palladium-catalyzed C-allylation of benzoins and an NHC-catalyzed three component coupling derived thereof: compatibility of NHC- and Pd-catalysts.

Org. Lett. 10 , 4243-4246, (2008)

A large range of benzoins was successfully applied as C-nucleophiles in the palladium-catalyzed allylic alkylation with several allyl acetates, resulting in functionalized tertiary homoallylic alcohol...

N-heterocyclic carbene-catalyzed hydroacylation of unactivated double bonds.

J. Am. Chem. Soc. 131 , 14190-14190, (2009)

An intramolecular N-heterocyclic carbene (NHC)-catalyzed hydroacylation of unactivated double bonds is reported. Systematic variation of the catalyst structure revealed an N-mesitylthiazolylidene annu...

N-heterocyclic carbene-catalyzed cascade reaction involving the hydroacylation of unactivated alkynes.

J. Am. Chem. Soc. 132 , 5970-5971, (2010)

The N-heterocyclic carbene (NHC)-catalyzed hydroacylation of unactivated alkynes to provide alpha,beta-unsaturated ketones is reported. In addition, a rare case of an efficient and selective dually NH...

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