DI-TERT-BUTYL DISULFIDE
Names
[ CAS No. ]:
110-06-5
[ Name ]:
DI-TERT-BUTYL DISULFIDE
[Synonym ]:
1,2-Di-tert-butyldisulfane
DI-TERT-BUTYLDISULFIDE
Disulfide, bis(1,1-dimethylethyl)
MFCD00008838
Di-tert-butyl disulfide
2,2'-disulfanediylbis(2-methylpropane)
EINECS 203-734-1
2-(tert-Butyldisulfanyl)-2-methylpropane
2-Methyl-2-[(2-methyl-2-propanyl)disulfanyl]propane
tert-Butyl Disulfide
Chemical & Physical Properties
[ Density]:
0.9±0.1 g/cm3
[ Boiling Point ]:
200.5±0.0 °C at 760 mmHg
[ Melting Point ]:
-5 °C
[ Molecular Formula ]:
C8H18S2
[ Molecular Weight ]:
178.359
[ Flash Point ]:
62.2±0.0 °C
[ Exact Mass ]:
178.084991
[ PSA ]:
50.60000
[ LogP ]:
4.23
[ Vapour density ]:
5 (vs air)
[ Vapour Pressure ]:
0.5±0.3 mmHg at 25°C
[ Index of Refraction ]:
1.495
[ Storage condition ]:
2-8°C
MSDS
Safety Information
[ Symbol ]:
GHS09
[ Hazard Statements ]:
H411
[ Precautionary Statements ]:
P273
[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
R36/37/38;R43
[ Safety Phrases ]:
S61
[ RIDADR ]:
UN 3082 9/PG 3
[ WGK Germany ]:
2
[ Packaging Group ]:
III
[ Hazard Class ]:
6.1(b)
[ HS Code ]:
2930909090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2930909090
[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%
Articles
Langmuir 10(3) , 761-66, (1994)
Enantioselective oxidation of di-tert-butyl disulfide with a vanadium catalyst: progress toward mechanism elucidation.
J. Org. Chem. 68(1) , 150-5, (2003)
The mechanism of the oxidation of di-tert-butyl disulfide (1) to the chiral thiosulfinate (2) by H(2)O(2) catalyzed by bis(acetylacetonato)oxovanadium and a chiral Schiff-base ligand (3) has been inve...