Trihydrido(pyridine)boron
Names
[ CAS No. ]:
110-51-0
[ Name ]:
Trihydrido(pyridine)boron
[Synonym ]:
Pyridine Borane
Borane pyridine complex
boron,pyridine
Boron, trihydro(pyridine)-
EINECS 203-773-4
Trihydrido(pyridine)boron
MFCD00012435
Borane - Pyridine CoMplex
Chemical & Physical Properties
[ Density]:
0.929 g/mL at 20 °C
[ Boiling Point ]:
102 °C (0.37505 mmHg)
[ Melting Point ]:
10-11 °C(lit.)
[ Molecular Formula ]:
C5H8BN
[ Molecular Weight ]:
92.935
[ Flash Point ]:
70 °F
[ Exact Mass ]:
93.074982
[ PSA ]:
4.93000
[ Vapour Pressure ]:
22.8mmHg at 25°C
[ Index of Refraction ]:
n20/D 1.532(lit.)
[ Storage condition ]:
2-8°C
[ Water Solubility ]:
reacts slowly
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- US3675000
- CHEMICAL NAME :
- Pyridine compd. with boron hydride
- CAS REGISTRY NUMBER :
- 110-51-0
- LAST UPDATED :
- 199709
- DATA ITEMS CITED :
- 5
- MOLECULAR FORMULA :
- C5-H8-B-N
- MOLECULAR WEIGHT :
- 92.95
- WISWESSER LINE NOTATION :
- T6NJ XBHHHH
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 95400 ug/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 14KTAK "Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New York, John Wiley & Sons, Inc., 1964 Volume(issue)/page/year: -,693,1964
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 64800 ug/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 14KTAK "Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New York, John Wiley & Sons, Inc., 1964 Volume(issue)/page/year: -,693,1964
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - guinea pig
- DOSE/DURATION :
- 200 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 14KTAK "Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New York, John Wiley & Sons, Inc., 1964 Volume(issue)/page/year: -,693,1964
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - guinea pig
- DOSE/DURATION :
- 54 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 14KTAK "Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New York, John Wiley & Sons, Inc., 1964 Volume(issue)/page/year: -,693,1964
Safety Information
[ Symbol ]:
GHS02, GHS06
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H225-H301-H310 + H330-H315-H319
[ Precautionary Statements ]:
P210-P260-P280-P284-P301 + P310-P302 + P350
[ Hazard Codes ]:
F:Flammable;T+:Verytoxic;
[ Risk Phrases ]:
R10;R15;R20;R24/25;R26;R36/37/38;R44
[ Safety Phrases ]:
S26-S36/37-S43-S45-S36/37/39-S28A
[ RIDADR ]:
UN 1992 3/PG 2
[ WGK Germany ]:
2
[ RTECS ]:
US3675000
[ Packaging Group ]:
II
[ Hazard Class ]:
4.3
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Articles
Macromol. Biosci. 15 , 1283-95, (2015)
Establishment of drug delivery system (DDS) in bone substitute materials for local treatment of bone defects still requires ambitious solutions for a retarded drug release. We present two novel DDS, a...
Hydroboration with pyridine borane at room temperature.J. Am. Chem. Soc. 127 , 5766-5767, (2005)
Treatment of pyridine borane (Py.BH3) with iodine, bromine, or strong acids affords activated Py.BH2X complexes that are capable of hydroborating alkenes at room temperature. Evidence is presented for...
Global amine and acid functional group modification of proteins.Anal. Chem. 80(3) , 713-20, (2008)
A sequential reaction methodology is employed for the complete derivatization of protein thiols, amines, and acids in high purity under denaturing conditions. Following standard thiol alkylation, prot...