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(r,s)-n-nitrosoanabasine

Names

[ CAS No. ]:
1133-64-8

[ Name ]:
(r,s)-n-nitrosoanabasine

[Synonym ]:
n-nitrosoanabasine
3-(1-nitroso-2-piperidyl)pyridine
1-nitrosoanabasine
(s)-3-(1-nitroso-2-piperidinyl)pyridine
MFCD01081833
(S)-1-Nitroso-1,2,3,4,5,6-hexahydro-[2,3']bipyridyl
3-(1-nitrosopiperidin-2-yl)pyridine
1-nitroso-anabasin
3-[(2S)-1-Nitroso-2-piperidinyl]pyridine
(S)-N-Nitroso Anabasine

Chemical & Physical Properties

[ Density]:
1.24g/cm3

[ Boiling Point ]:
380.2ºC at 760mmHg

[ Molecular Formula ]:
C10H13N3O

[ Molecular Weight ]:
191.23000

[ Flash Point ]:
9℃

[ Exact Mass ]:
191.10600

[ PSA ]:
45.56000

[ LogP ]:
2.22790

[ Vapour Pressure ]:
1.21E-05mmHg at 25°C

[ Index of Refraction ]:
1.624

[ Storage condition ]:
?20°C

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BV4550000
CHEMICAL NAME :
Anabasine, 1-nitroso-
CAS REGISTRY NUMBER :
1133-64-8
LAST UPDATED :
199506
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C10-H13-N3-O
MOLECULAR WEIGHT :
191.26
WISWESSER LINE NOTATION :
T6NTJ ANO B- CT6NJ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
6000 mg/kg/50W-I
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Gastrointestinal - tumors
REFERENCE :
BJCAAI British Journal of Cancer. (Macmillan Press Ltd., Houndmills, Basingstoke, Hants. RG21 2XS, UK) V.1- 1947- Volume(issue)/page/year: 18,265,1964
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1030 mg/kg/7W-I
TOXIC EFFECTS :
Tumorigenic - neoplastic by RTECS criteria Lungs, Thorax, or Respiration - tumors
REFERENCE :
CALEDQ Cancer Letters (Shannon, Ireland). (Elsevier Scientific Pub. Ireland Ltd., POB 85, Limerick, Ireland) V.1- 1975- Volume(issue)/page/year: 71,25,1993

Safety Information

[ Symbol ]:

GHS02, GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H301 + H311 + H331-H370

[ Precautionary Statements ]:
P210-P260-P280-P301 + P310-P311

[ Hazard Codes ]:
F,T

[ Risk Phrases ]:
11-23/24/25-39/23/24/25

[ Safety Phrases ]:
7-16-36/37-45

[ RIDADR ]:
UN1230 - class 3 - PG 2 - Methanol, solution

[ HS Code ]:
2933990090

Synthetic Route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2933990090

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Oral mucosal changes and nicotine disposition in users of Swedish smokeless tobacco products: a comparative study.

J. Oral. Pathol. Med. 23(4) , 161-7, (1994)

The purpose of this study was to investigate the uptake and metabolism of nicotine by smokeless (oral) tobacco users and to find out if the less pronounced clinical changes in the oral mucosa in users...

N'-Nitrosoanabasine (NAB).

IARC Monogr. Eval. Carcinog. Risk Chem. Hum. 37 , 225-31, (1985)

Immunotoxic effects of smokeless tobacco on the accessory cell function of rat oral epithelium.

Eur. J. Oral Sci. 105(1) , 45-51, (1997)

Smokeless tobacco (ST) is known to adversely effect the oral mucosa, but knowledge about the influence on immune defence is limited. Few studies have investigated the effect of ST on the local immune ...


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