4-Methoxy-3-nitrotoluene
Names
[ CAS No. ]:
119-10-8
[ Name ]:
4-Methoxy-3-nitrotoluene
[Synonym ]:
4-Methoxy-3-nitrotoluene
EINECS 204-296-4
BENZENE,1-METHOXY-4-METHYL-2-NITRO-
1-Methoxy-4-methyl-2-nitrobenzene
WNR C1 FO1
Methyl 4-methyl-2-nitrophenyl ether
Anisole, 4-methyl-2-nitro-
MFCD00024540
BENZENE,1-METHOXY-4-METHYL-2-NITRO
Benzene, 1-methoxy-4-methyl-2-nitro-
Chemical & Physical Properties
[ Density]:
1.2±0.1 g/cm3
[ Boiling Point ]:
289.4±0.0 °C at 760 mmHg
[ Melting Point ]:
8-9 °C(lit.)
[ Molecular Formula ]:
C8H9NO3
[ Molecular Weight ]:
167.162
[ Flash Point ]:
136.1±23.8 °C
[ Exact Mass ]:
167.058243
[ PSA ]:
55.05000
[ LogP ]:
2.19
[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C
[ Index of Refraction ]:
1.538
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H302-H319
[ Precautionary Statements ]:
P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xn:Harmful;
[ Risk Phrases ]:
R22
[ Safety Phrases ]:
26-36
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2909309090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2909309090
[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
Articles
Acta Crystallogr. Sect. E Struct. Rep. Online 65(9) , o2193-94, (2009)
The asymmetric unit of the title compound, C(8)H(7)Br(2)NO(3), comprises two crystallographically independent mol-ecules (A and B). The nitro groups are twisted from the attached benzene rings, making...
Theoretical calculations of chemical interactions. Part 4. Aromatic nucleophilic substitutions and SN 2 reactions of 4-and 6-substituted 2-nitroanisoles. Nudelman NS and Palleros DR.J. Chem. Soc., Perkin Trans. II 6 , 805-9, (1985)