2,2-DIMETHYLCYCLOHEXANONE

Names

[ Name ]:
2,2-DIMETHYLCYCLOHEXANONE

[Synonym ]:
MFCD00134382
2,2-DIMETHYLCYCLOHEXANON
2,2-Dimethyl-cyclohexanon
CYCLOHEXANONE,2,2-DIMETHYL-
2,2-Dimethyl-Cyclohexanone
2 2-DIMETHYLCYCLOHEXANONE
2,2-Dimethylcyclohexanone
2,2-dimethylcyclohexan-1-one
2,2-Dimethyl-1-cyclohexanone
2,2-Dimethyl cyclohexan-1-one
2,2-DIMETHYL-4-(3-METHOXY-4-METHYLPHENYL)-4-OXOBUTYRIC ACID
6,6-dimethylcyclohexanone

Chemical & Physical Properties

[ Density]:
0.892g/cm3

[ Boiling Point ]:
170.6ºC at 760mmHg

[ Melting Point ]:
-20ºC(lit.)

[ Molecular Formula ]:
C₈H₁₄O

[ Molecular Weight ]:
126.19600

[ Flash Point ]:
50.1ºC

[ Exact Mass ]:
126.10400

[ PSA ]:
17.07000

[ LogP ]:
2.15570

[ Appearance of Characters ]:
Liquid | Clear colorless to yellow

[ Vapour Pressure ]:
1.46mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.448(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Risk Phrases ]:
R10

[ Safety Phrases ]:
S16

[ RIDADR ]:
UN 1224 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2914299000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2914299000

[ Summary ]:
2914299000. other cyclanic, cyclenic or cyclotherpenic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Dichloromethane activation. Direct methylenation of ketones and aldehydes with CH2Cl2 promoted by Mg/TiCl4/THF.

Org. Lett. 6(26) , 4961-3, (2004)

[reaction: see text] This Mg-TiCl4-promoted CH2-transfer reaction of CH2Cl2 represents an extremely simple, practical, and efficient methylenation of a variety of ketones and aldehydes, especially in ...

Synthesis and antioxidant activity of rosmariquinone and several analogues. Hall CA, et al.

J. Agric. Food Chem. 46(4) , 1303-10, (1998)