Chlorocyclopentadienyl[(4R,5R)-2,2-dimethyl-α,α,α′,α ′-tetraphenyl-1,3-dioxolane-4,5-dimethanolato]titanium

Names

[ CAS No. ]:
132068-98-5

[ Name ]:
Chlorocyclopentadienyl[(4R,5R)-2,2-dimethyl-α,α,α′,α ′-tetraphenyl-1,3-dioxolane-4,5-dimethanolato]titanium

[Synonym ]:
(R,R)-Duthaler-Hafner reagent
[(4R,5R)-2,2-Dimethyl-1,3-dioxolan-4,5-bis(diphenylmethoxy)]cyclopentadienyl-chlorotitanium
Chlorocyclopentadienyl[(4R,5R)-2,2-dimethyl-|A,|A,|A inverted exclamation marka,|A inverted exclamation marka-tetraphenyl-1,3-dioxolane-4,5-dimethanolato]titanium
MFCD00143370
(4R,5R)-Chloro-cyclopentadienyl-[2,2-dimethyl-1,3-dioxolan-4,5-bis(diphenylmethoxy)]titanium

Chemical & Physical Properties

[ Melting Point ]:
209-213ºC

[ Molecular Formula ]:
C₃₆H₃₃ClO₄Ti

[ Molecular Weight ]:
612.96500

[ Exact Mass ]:
612.15500

[ PSA ]:
64.58000

[ LogP ]:
4.57580

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26;S45;S36/S37/S39

[ RIDADR ]:
UN 3261 8/PG 2

Articles

A. Hafner et al.

J. Am. Chem. Soc. 114 , 2321, (1992)

Duthaler, R.O. Hafner, A.

Chem. Rev. 92 , 807, (1992)

Duthaler, R.O. et al.

Pure Appl. Chem. 64 , 1897, (1990)