Gallium trichloride
Names
[ CAS No. ]:
13450-90-3
[ Name ]:
Gallium trichloride
[Synonym ]:
MFCD00011018
gallium chloride
GaCl3
gallium(III) chloride
Gallium trichloride
EINECS 236-610-0
trichlorogallane
Trichlorogallium
Chemical & Physical Properties
[ Density]:
2.47
[ Boiling Point ]:
201.03ºC
[ Melting Point ]:
77.9ºC
[ Molecular Formula ]:
Cl3Ga
[ Molecular Weight ]:
176.082
[ Flash Point ]:
-26 °F
[ Exact Mass ]:
173.832138
[ LogP ]:
1.68770
[ Vapour Pressure ]:
33900mmHg at 25°C
[ Stability ]:
Stability Stable, but reacts violently with water.
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- LW9100000
- CHEMICAL NAME :
- Gallium(3+) chloride
- CAS REGISTRY NUMBER :
- 13450-90-3
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 10
- MOLECULAR FORMULA :
- Cl3-Ga
- MOLECULAR WEIGHT :
- 176.07
- WISWESSER LINE NOTATION :
- GA G3
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LCLo - Lowest published lethal concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 316 mg/m3/3H
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 306 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 47 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Parenteral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1408 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 36975 ug/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Mammal - dog
- DOSE/DURATION :
- 41 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 245 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 43 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
MUTATION DATA
- TYPE OF TEST :
- DNA repair
- TEST SYSTEM :
- Bacteria - Bacillus subtilis
- DOSE/DURATION :
- 2350 ug/disc
- REFERENCE :
- MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 264,163,1991
Safety Information
[ Symbol ]:
GHS02, GHS05, GHS07, GHS08, GHS09
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H224-H304-H314-H336-H411
[ Supplemental HS ]:
Reacts violently with water.
[ Precautionary Statements ]:
P210-P261-P273-P280-P301 + P310-P305 + P351 + P338
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US)
[ Hazard Codes ]:
C: Corrosive;
[ Risk Phrases ]:
R14;R34
[ Safety Phrases ]:
26-27-28-36/37/39-45
[ RIDADR ]:
UN 3260
[ WGK Germany ]:
3
[ RTECS ]:
LW9100000
[ Packaging Group ]:
II
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Articles
Anal. Chem. 87 , 6890-5, (2015)
Mercury is a highly toxic heavy metal, and detection of Hg(2+) by biosensors has attracted extensive research interest in the past decade. In particular, a number of DNA-based sensing strategies have ...
Isolation and structure determination of new siderophore albachelin from Amycolatopsis alba.Biometals 28(2) , 381-9, (2015)
A new siderophore named albachelin was isolated from iron deficient culture of Amycolatopsis alba. The planar structure of albachelin was elucidated by the combination of ESI-MS/MS experiment and NMR ...
Cyclopropylmethylation of benzylic and allylic chlorides with cyclopropylmethylstannane catalyzed by gallium or indium halide.Org. Lett. 12(7) , 1520-3, (2010)
Benzylic and allylic chlorides easily coupled with cyclopropylmethylstannane in the presence of GaCl(3) or InBr(3) catalyst, in which an intermediate of an active butenylgallium or -indium species was...