PENTAFLUOROPHENYL CHLOROTHIONOFORMATE
Names
[ CAS No. ]:
135192-53-9
[ Name ]:
PENTAFLUOROPHENYL CHLOROTHIONOFORMATE
[Synonym ]:
Pentafluorophenyl Chlorothionoformate
Pentafluorophenyl Thionochloroformate
Chlorothioformic Acid O-Pentafluorophenyl Ester
pentafluorophenoxythiocarbonyl chloride
pentafluorophenyloxythiocarbonyl chloride
O-Perfluorophenyl Chlorothioformate
O-pentafluorophenyl chlorothionoformate
O-pentafluorophenyl chlorothioformate
P1267
MFCD00075405
O-perfluorophenyl carbonochloridethioate
Chemical & Physical Properties
[ Density]:
1.635 g/mL at 25ºC(lit.)
[ Boiling Point ]:
98-102ºC50 mm Hg(lit.)
[ Molecular Formula ]:
C7ClF5OS
[ Molecular Weight ]:
262.58400
[ Flash Point ]:
189 °F
[ Exact Mass ]:
261.92800
[ PSA ]:
41.32000
[ LogP ]:
3.28460
[ Vapour Pressure ]:
1.03mmHg at 25°C
[ Index of Refraction ]:
n20/D 1.481(lit.)
MSDS
Safety Information
[ Symbol ]:
GHS05
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H314
[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
C
[ Risk Phrases ]:
34
[ Safety Phrases ]:
26-27-36/37/39-45
[ RIDADR ]:
UN 3265 8/PG 2
[ HS Code ]:
2930909090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2930909090
[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%
Articles
Org. Lett. 2(2) , 227-30, (2000)
[structures: see text] A regio- and stereoselective glycosylation of ribose tetraester with persilylated alloxazine to give either beta-N1 or beta-N3 nucleosides is described. The N3 product is potent...
Tuning the acceptors in catalyzed cyclizations initiated by allenes. Silylstannylation/cyclization of allene-aldehydes for synthesis of polyalkylated indolizidines including 223A congeners.J. Org. Chem. 69(26) , 9151-8, (2004)
Starting from succinamide and 1,2-heptadiene-4-ol, a racemic allene-aldehyde substrate, 20, suitable for R(3)SiSnR'(3)-mediated cyclization was synthesized in six steps and in 21% yield. Stereoselecti...
The invention of radical reactions. Part XXI. Simple methods for the radical deoxygenation of primary alcohols. Barton DHR, et al.Tetrahedron 47(43) , 8969-94, (1991)