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PENTAFLUOROPHENYL CHLOROTHIONOFORMATE

Names

[ CAS No. ]:
135192-53-9

[ Name ]:
PENTAFLUOROPHENYL CHLOROTHIONOFORMATE

[Synonym ]:
Pentafluorophenyl Chlorothionoformate
Pentafluorophenyl Thionochloroformate
Chlorothioformic Acid O-Pentafluorophenyl Ester
pentafluorophenoxythiocarbonyl chloride
pentafluorophenyloxythiocarbonyl chloride
O-Perfluorophenyl Chlorothioformate
O-pentafluorophenyl chlorothionoformate
O-pentafluorophenyl chlorothioformate
P1267
MFCD00075405
O-perfluorophenyl carbonochloridethioate

Chemical & Physical Properties

[ Density]:
1.635 g/mL at 25ºC(lit.)

[ Boiling Point ]:
98-102ºC50 mm Hg(lit.)

[ Molecular Formula ]:
C7ClF5OS

[ Molecular Weight ]:
262.58400

[ Flash Point ]:
189 °F

[ Exact Mass ]:
261.92800

[ PSA ]:
41.32000

[ LogP ]:
3.28460

[ Vapour Pressure ]:
1.03mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.481(lit.)

MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C

[ Risk Phrases ]:
34

[ Safety Phrases ]:
26-27-36/37/39-45

[ RIDADR ]:
UN 3265 8/PG 2

[ HS Code ]:
2930909090

Synthetic Route

Precursor & DownStream

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Regioselective synthesis of beta-N1- and beta-N3-alloxazine nucleosides

Org. Lett. 2(2) , 227-30, (2000)

[structures: see text] A regio- and stereoselective glycosylation of ribose tetraester with persilylated alloxazine to give either beta-N1 or beta-N3 nucleosides is described. The N3 product is potent...

Tuning the acceptors in catalyzed cyclizations initiated by allenes. Silylstannylation/cyclization of allene-aldehydes for synthesis of polyalkylated indolizidines including 223A congeners.

J. Org. Chem. 69(26) , 9151-8, (2004)

Starting from succinamide and 1,2-heptadiene-4-ol, a racemic allene-aldehyde substrate, 20, suitable for R(3)SiSnR'(3)-mediated cyclization was synthesized in six steps and in 21% yield. Stereoselecti...

The invention of radical reactions. Part XXI. Simple methods for the radical deoxygenation of primary alcohols. Barton DHR, et al.

Tetrahedron 47(43) , 8969-94, (1991)


More Articles


Related Compounds