tert-butyl tetraisopropylphosphorodiamidite

Names

[ Name ]:
tert-butyl tetraisopropylphosphorodiamidite

[Synonym ]:
Phosphorodiamidousacid,N,N,N',N'-tetrakis(1-methylethyl)-,1,1-dimethylethyl ester
[tert-butyloxy]bis(N,N-diisopropylamino)phosphane
tert-butyl N,N,N',N'-tetraisopropylphosphorodiamidite
tert-butyl tetraisopropylphosphordiamidite
Phosphorodiamidousacid,tetrakis(1-methylethyl)-,1,1-dimethylethyl ester (9CI)
tert-Butyl tetraisopropylphosphorodiamidite
(tert-Butoxy)bis(diisopropylamino)phosphine

Chemical & Physical Properties

[ Boiling Point ]:
330.1ºC at 760mmHg

[ Melting Point ]:
67-74ºC(lit.)

[ Molecular Formula ]:
C₁₆H₃₇N₂OP

[ Molecular Weight ]:
304.45200

[ Flash Point ]:
153.4ºC

[ Exact Mass ]:
304.26400

[ PSA ]:
29.30000

[ LogP ]:
5.26600

[ Vapour Pressure ]:
0.00017mmHg at 25°C

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Articles

High relaxivity magnetic resonance imaging contrast agents. Part 1. Impact of single donor atom substitution on relaxivity of serum albumin-bound gadolinium complexes.

Invest. Radiol. 45(10) , 600-12, (2010)

The donor atoms that bind to gadolinium in contrast agents influence inner-sphere water exchange and electronic relaxation, both of which determine observed relaxivity. The effect of these molecular p...

Palladium-Catalysed Amination of Aryl-and Heteroaryl Halides Using tert-Butyl Tetraisopropylphosphorodiamidite as an Easily Accessible and Air-Stable Ligand. Roiban G-D, et al.

European J. Org. Chem. 10 , 2070-2076, (2014)