Dinoterb

Names

[ Name ]:
Dinoterb

[Synonym ]:
2-(TERT-BUTYL)-4,6-DINITROPHENOL
Dinoterb
Herbogil
Dinoterb PESTANAL(R),analytical standard
2-(1,1-dimethylethyl)-4,6-dinitrophenol
2-tert-butyl-4,6-dinitrophenol
Dntbp
EINECS 215-813-8
2,4-dinitro-6-tert-butylphenol
Dinoterbe
MFCD00031117
Phenol, 2-(1,1-dimethylethyl)-4,6-dinitro-
Caswell No. 392F
Stirpan forte
2-t-butyl-4,6-dinitrophenol
Phenol,2-tert-butyl-4,6-dinitro
2-(2-Methyl-2-propanyl)-4,6-dinitrophenol

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
304.2±42.0 °C at 760 mmHg

[ Melting Point ]:
125.5-126.5ºC

[ Molecular Formula ]:
C₁₀H₁₂N₂O₅

[ Molecular Weight ]:
240.213

[ Flash Point ]:
125.0±16.3 °C

[ Exact Mass ]:
240.074615

[ PSA ]:
111.87000

[ LogP ]:
3.42

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.584

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: SK0160000

CHEMICAL NAME :: Phenol, o-t-butyl-4,6-dinitro-

CAS REGISTRY NUMBER :: 1420-07-1

BEILSTEIN REFERENCE NO. :: 1887173

LAST UPDATED :: 199710

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C10-H12-N2-O5

MOLECULAR WEIGHT :: 240.24

WISWESSER LINE NOTATION :: WNR BQ ENW CX1&1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 26 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 26,69,1972

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 19500 ug/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A161,1985

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 28300 ug/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A161,1985

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 150 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 28ZEAL "Pesticide Index," Frear, E.H., ed., State College, PA, College Science Pub., 1969 Volume(issue)/page/year: 5,82,1976

Safety Information

[ Symbol ]:

GHS06, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H300-H311-H360D-H410

[ Supplemental HS ]:
Risk of explosion if heated under confinement.

[ Precautionary Statements ]:
P201-P264-P273-P280-P301 + P310-P308 + P313

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ Hazard Codes ]:
T+,N

[ Risk Phrases ]:
61-24-28-44-50/53

[ Safety Phrases ]:
53-45-60-61

[ RIDADR ]:
2779

[ WGK Germany ]:
3

[ RTECS ]:
SK0160000

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1(a)

[ HS Code ]:
2908999024

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2908999024

[ Summary ]:
2908999024 2-(tert-butyl)-4,6-dinitrophenol。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:0.0%。MFN tarrif:5.5%。general tariff:30.0%

Articles

Differential pulse adsorptive stripping voltammetric determination of dinoseb and dinoterb at a modified electrode.

Anal. Sci. 19(4) , 511-6, (2003)

A sensitive adsorptive stripping voltammetric method for the determination of dinitrophenolic herbicides, dinoseb (DSB) and dinoterb (DTB) at a bare carbon paste electrode (CPE) and a clay modified ca...

[Use of the analytical method LC-MS/MS for finding dinoseb and dinoterb in agricultural products, livestock products and seafood].

Shokuhin Eiseigaku Zasshi 54(1) , 1-6, (2013)

A simple determination method of dinoseb and dinoterb in agricultural products, livestock products and seafood by LC-MS/MS was developed. Agricultural samples were extracted with acetone (in the case ...

Evaluation of a TiO2 photocatalysis treatment on nitrophenols and nitramines contaminated plant wastewaters by solid-phase extraction coupled with ESI HPLC-MS.

J. Hazard. Mater. 166(1) , 284-90, (2009)

Nitration reactions of aromatic compounds are commonly involved in different industrial processes for pharmaceutical, pesticide or military uses. For many years, most of the manufacturing sites used l...