2-(Tributylstannyl)-1,3-oxazole

Names

[ Name ]:
2-(Tributylstannyl)-1,3-oxazole

[Synonym ]:
tributylstannyloxazole
2-(Tri-n-butylstannyl)oxazole
2-(Tributylstannyl)-1,3-oxazole
2-tributylstannanyl-oxazole
2-(Tributylstannyl)oxazole
Oxazole,2-(tributylstannyl)
MFCD06798076
Oxazole, 2-(tributylstannyl)-
2-(tributylstannanyl)-1,3-oxazole
oxazole-2-SnBu3

Chemical & Physical Properties

[ Density]:
1.71 g/mL at 25ºC(lit.)

[ Boiling Point ]:
340.6±25.0 °C at 760 mmHg

[ Melting Point ]:
227-228℃

[ Molecular Formula ]:
C₁₅H₂₉NOSn

[ Molecular Weight ]:
358.107

[ Flash Point ]:
159.8±23.2 °C

[ Exact Mass ]:
359.127106

[ PSA ]:
26.03000

[ LogP ]:
8.61

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.4930(lit.)

[ Water Solubility ]:
Insoluble in water.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS06, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H312-H315-H319-H372-H410

[ Precautionary Statements ]:
Missing Phrase - N15.00950417-P260-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T: Toxic;N: Dangerous for the environment;

[ Risk Phrases ]:
R21

[ Safety Phrases ]:
S35

[ RIDADR ]:
UN 2788 6.1/PG 3

[ WGK Germany ]:
3

[ HS Code ]:
2934999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2934999090

[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Synthesis of the eastern portion of ajudazol a based on Stille coupling and double acetylene carbocupration.

Org. Lett. 7 , 1063, (2005)

[structure: see text] A strategy for the synthesis of ajudazol A, an unusual, pharmacologically active metabolite from myxobacteria, based on the Stille cross-coupling of a 2-stannyl-oxazole with a vi...