Cyclopropanecarboxyldehyde
Names
[ CAS No. ]:
1489-69-6
[ Name ]:
Cyclopropanecarboxyldehyde
[Synonym ]:
Cyclopropanecarboxaldehyde
MFCD00012261
Cyclopropanecarbaldehyde
Chemical & Physical Properties
[ Density]:
1.2±0.1 g/cm3
[ Boiling Point ]:
99.5±0.0 °C at 760 mmHg
[ Molecular Formula ]:
C4H6O
[ Molecular Weight ]:
70.090
[ Flash Point ]:
7.2±0.0 °C
[ Exact Mass ]:
70.041862
[ PSA ]:
17.07000
[ LogP ]:
0.21
[ Vapour Pressure ]:
38.2±0.1 mmHg at 25°C
[ Index of Refraction ]:
1.599
[ Storage condition ]:
Refrigerator
MSDS
Safety Information
[ Symbol ]:
GHS02, GHS05
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H225-H314
[ Precautionary Statements ]:
P210-P280-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
F:Flammable;C:Corrosive;
[ Risk Phrases ]:
R11;R34
[ Safety Phrases ]:
S16-S26-S36/37/39-S45
[ RIDADR ]:
UN 2924 3/PG 2
[ WGK Germany ]:
3
[ RTECS ]:
GZ1005000
[ Packaging Group ]:
II
[ Hazard Class ]:
3
[ HS Code ]:
2912299000
Synthetic Route
Customs
[ HS Code ]: 2912299000
[ Summary ]:
2912299000. other cyclic aldehydes without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%
Articles
Chemistry 15(39) , 10083-91, (2009)
Cyclopropanecarboxaldehyde (1 a), cyclopropyl methyl ketone (1 b), and cyclopropyl phenyl ketone (1 c) were reacted with [Ni(cod)(2)] (cod = 1,5-cyclooctadiene) and PBu(3) at 100 degrees C to give eta...
Wang, Z. et alTetrahedron Lett. 41 , 4007, (2000)
Palladium-catalyzed asymmetric [3 + 2] trimethylenemethane cycloaddition reactions.
J. Am. Chem. Soc. 128 , 13328, (2006)
Transition-metal-catalyzed trimethylenemethane (TMM) [3 + 2] cycloadditions provide direct routes to functionalized cyclopentanes. This reaction has been shown to be a highly chemo-, regio-, and diast...