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Cyclopropanecarboxyldehyde

Names

[ CAS No. ]:
1489-69-6

[ Name ]:
Cyclopropanecarboxyldehyde

[Synonym ]:
Cyclopropanecarboxaldehyde
MFCD00012261
Cyclopropanecarbaldehyde

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
99.5±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C4H6O

[ Molecular Weight ]:
70.090

[ Flash Point ]:
7.2±0.0 °C

[ Exact Mass ]:
70.041862

[ PSA ]:
17.07000

[ LogP ]:
0.21

[ Vapour Pressure ]:
38.2±0.1 mmHg at 25°C

[ Index of Refraction ]:
1.599

[ Storage condition ]:
Refrigerator

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H314

[ Precautionary Statements ]:
P210-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable;C:Corrosive;

[ Risk Phrases ]:
R11;R34

[ Safety Phrases ]:
S16-S26-S36/37/39-S45

[ RIDADR ]:
UN 2924 3/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
GZ1005000

[ Packaging Group ]:
II

[ Hazard Class ]:
3

[ HS Code ]:
2912299000

Synthetic Route

Customs

[ HS Code ]: 2912299000

[ Summary ]:
2912299000. other cyclic aldehydes without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Synthesis and reactivity of six-membered oxa-nickelacycles: a ring-opening reaction of cyclopropyl ketones.

Chemistry 15(39) , 10083-91, (2009)

Cyclopropanecarboxaldehyde (1 a), cyclopropyl methyl ketone (1 b), and cyclopropyl phenyl ketone (1 c) were reacted with [Ni(cod)(2)] (cod = 1,5-cyclooctadiene) and PBu(3) at 100 degrees C to give eta...

Wang, Z. et al

Tetrahedron Lett. 41 , 4007, (2000)

Palladium-catalyzed asymmetric [3 + 2] trimethylenemethane cycloaddition reactions.

J. Am. Chem. Soc. 128 , 13328, (2006)

Transition-metal-catalyzed trimethylenemethane (TMM) [3 + 2] cycloadditions provide direct routes to functionalized cyclopentanes. This reaction has been shown to be a highly chemo-, regio-, and diast...


More Articles


Related Compounds