3-Bromocyclohexene

Names

[ CAS No. ]:
1521-51-3

[ Name ]:
3-Bromocyclohexene

[Synonym ]:
3-Bromocyclohex-1-ene
1,2,3,4-Tetrahydrobromobenzene
MFCD00013775
3-BroMocyclohexene

Chemical & Physical Properties

[ Density]:
1.4 g/mL at 25 °C(lit.)

[ Boiling Point ]:
57-58 °C12 mm Hg(lit.)

[ Molecular Formula ]:
C₆H₉Br

[ Molecular Weight ]:
161.04000

[ Flash Point ]:
130 °F

[ Exact Mass ]:
159.98900

[ LogP ]:
2.49000

[ Vapour Pressure ]:
5.49mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.528(lit.)

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R10

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ HS Code ]:
2903890090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2903890090

[ Summary ]:
2903890090. halogenated derivatives of cyclanic, cyclenic or cyclotherpenic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

An efficient synthesis of N-tert-butoxycarbonyl-O-cyclohexyl-L-tyrosine.

Chem. Pharm. Bull. 49(2) , 233-5, (2001)

A facile and efficient synthesis of N-tert-butoxycarbonyl-O-cyclohexyl-L-tyrosine [Boc-Tyr(Chx)-OH] is described. Boc-Tyr-OH was treated with NaH in dimethylformamide and then with 3-bromocyclohexene ...

Synthesis of enantiopure cyclitols from (±)-3-bromocyclohexene mediated by intramolecular oxyselenenylation employing (S, S)-hydrobenzoin and (S)-mandelic acid as chiral sources. Lee YJ, et al.

Tetrahedron 61(8) , 1987-2001, (2005)