N,N'-(11R,12R)-(9,10-Dihydro-9,10-ethanoanthracene-11,12-diyl)bis[2-(diphenylphosphino)benzamide]
Names
[ CAS No. ]:
152140-65-3
[ Name ]:
N,N'-(11R,12R)-(9,10-Dihydro-9,10-ethanoanthracene-11,12-diyl)bis[2-(diphenylphosphino)benzamide]
[Synonym ]:
(R,R)-anthracenyl Trost ligand
(+)-(11R,12R)Bis[2 inverted exclamation marka-(diphenylphosphino)benzamido]-9,10-dihydro-9,10-ethanoanthracene
(11R,12R)-N,N inverted exclamation marka-(9,10-Dihydro-9,10-ethanoanthracene-11,12-diyl)bis[2-(diphenylphosphino)]benzamide
Chemical & Physical Properties
[ Molecular Formula ]:
C54H42N2O2P2
[ Molecular Weight ]:
812.87100
[ Exact Mass ]:
812.27200
[ PSA ]:
92.36000
[ LogP ]:
9.54060
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
[ Hazard Codes ]:
Xi
[ RIDADR ]:
NONH for all modes of transport
Articles
Chem. Rev. 96 , 395, (1996)
Asymmetric transition-metal-catalyzed allylic alkylations: applications in total synthesis.
Chem. Rev. 103 , 2921, (2003)
Trost, B.M. et al.
J. Am. Chem. Soc. 124 , 11616, (2004)