Di-(2-picolyl)amine

Names

[ Name ]:
Di-(2-picolyl)amine

[Synonym ]:
Di-2-picolylamine
bis(2-pyridylmethyl)amine
Iminobis(methylene-2-pyridine)
bis(pyridylmethyl)amine
2-Pyridinemethanamine, N- (2-pyridinylmethyl)-
bis-(2-picolyl)amine
α,α'-Iminodi(2-picoline)
2,2'-Dipicolylamine
MFCD00129044
1-(Pyridin-2-yl)-N-(pyridin-2-ylmethyl)methanamine
di-(2-picolyl)-amine
di(2-picolyl)amine
EINECS 216-266-8
1-(2-Pyridinyl)-N-(2-pyridinylmethyl)methanamine
Dipicolylamine
2-Pyridinemethanamine, N-(2-pyridinylmethyl)-
N,N-bis(2-picolyl)amine

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
322.2±27.0 °C at 760 mmHg

[ Molecular Formula ]:
C₁₂H₁₃N₃

[ Molecular Weight ]:
199.252

[ Flash Point ]:
148.6±23.7 °C

[ Exact Mass ]:
199.110947

[ PSA ]:
37.81000

[ LogP ]:
0.44

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.589

[ Water Solubility ]:
water: soluble (partially miscible)(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2933399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Identifying chelators for metalloprotein inhibitors using a fragment-based approach.

J. Med. Chem. 54 , 591-602, (2011)

Fragment-based lead design (FBLD) has been used to identify new metal-binding groups for metalloenzyme inhibitors. When screened at 1 mM, a chelator fragment library (CFL-1.1) of 96 compounds produced...

Efficient hydrolytic cleavage of plasmid DNA by chloro-cobalt(II) complexes based on sterically hindered pyridyl tripod tetraamine ligands: synthesis, crystal structure and DNA cleavage.

Dalton Trans. 43(26) , 10086-103, (2014)

Four new cobalt(ii) complexes [Co(6-MeTPA)Cl]ClO4/PF6 (2/2a), [Co(6-Me2TPA)Cl]ClO4/PF6 (3/3a), [Co(BPQA)Cl]ClO4/PF6 (4/4a) and [Co(BQPA)Cl]ClO4/PF6 (5/5a) as well as [Co(TPA)Cl]ClO4 (1) where TPA = tr...

Formation of a metal-to-nitrogen bond of normal length by a neutral sufonamide group within a tridentate ligand. A new approach to radiopharmaceutical bioconjugation.

Inorg. Chem. 52(5) , 2412-21, (2013)

We demonstrate that a tertiary sulfonamide group, N(SO2R)R'2, can rehybridize to form a M-N bond of normal length even when the group is in a linear tridentate ligand, such as in the new tridentate N(...