Copper(1+) tetrafluoroborate acetonitrile (1:1:4)

Names

[ Name ]:
Copper(1+) tetrafluoroborate acetonitrile (1:1:4)

[Synonym ]:
Tetrakis(acetonitrile)copper(I) tetrafluoroborate
Copper(1+) tetrafluoroborate acetonitrile (1:1:4)
Copper(1+) tetrafluoroborate - acetonitrile (1:1:4)
acetonitrile,copper(1+),tetrafluoroborate

Chemical & Physical Properties

[ Melting Point ]:
164 °C(dec.)

[ Molecular Formula ]:
C₈H₁₂BCuF₄N₄

[ Molecular Weight ]:
314.558

[ Exact Mass ]:
314.038727

[ PSA ]:
95.16000

[ LogP ]:
3.41702

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C

[ Risk Phrases ]:
34

[ Safety Phrases ]:
26-36/37/39-45

[ RIDADR ]:
UN 1759 8/PG 2

[ Packaging Group ]:
III

Articles

Enantioselective aziridination using copper complexes of biaryl Schiff bases.

J. Org. Chem. 67 , 3450, (2002)

Racemic 2,2'-diamino-6,6'-dimethylbiphenyl is resolved using simulated moving bed chromatography, and the absolute configuration of the enantiomers is confirmed via the X-ray crystal structure of a de...

Catalytic enantioselective synthesis of quaternary all-carbon stereogenic centers. Preparation of alpha,alpha'-disubstituted beta,gamma-unsaturated esters through Cu-catalyzed asymmetric allylic alkylations.

Org. Lett. 7 , 1255, (2005)

[reaction: see text] Peptide-based chiral ligands, readily prepared from commercially available materials, are used to promote Cu-catalyzed asymmetric allylic alkylations of alpha,beta-unsaturated est...

Stoichiometry and cluster specificity of copper binding to metallothionein: homogeneous metal clusters.

Biochem. J. 317 ( Pt 2) , 395-402, (1996)

Experiments were done to define the stoichiometry of binding of Cu(I) to metallothionein (MT) and to determine its sites of binding in mixed-metal species. Spectrophotometric titrations of rabbit live...