n-trifluoroacetylimidazole

Names

[ Name ]:
n-trifluoroacetylimidazole

[Synonym ]:
n-trifluoroacetylimidazole
Ethanone, 2,2,2-trifluoro-1-(1H-imidazol-1-yl)-
1-(Trifluoroacetyl)iMidazole
2,2,2-trifluoro-1-imidazol-1-ylethanone
MFCD00014501
EINECS 216-282-5
2,2,2-Trifluoro-1-(1H-imidazol-1-yl)ethanone

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
151.4±50.0 °C at 760 mmHg

[ Molecular Formula ]:
C₅H₃F₃N₂O

[ Molecular Weight ]:
164.085

[ Flash Point ]:
45.0±0.0 °C

[ Exact Mass ]:
164.019745

[ PSA ]:
34.89000

[ LogP ]:
1.18

[ Vapour Pressure ]:
3.7±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.470

[ Storage condition ]:
0-6°C

[ Water Solubility ]:
reacts

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;Xi:Irritant;

[ Risk Phrases ]:
R10;R22;R34;R36/37/38

[ Safety Phrases ]:
S26-S36/37-S45-S36/37/39-S16

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
2933290090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2933290090

[ Summary ]:
2933290090. other compounds containing an unfused imidazole ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Determination of mustard gas hydrolysis products thiodiglycol and thiodiglycol sulfoxide by gas chromatography-tandem mass spectrometry after trifluoroacetylation.

Anal. Chem. 86(12) , 5865-72, (2014)

A method for detecting mustard gas degradation products thiodiglycol (TDG) and thiodiglycol sulfoxide (TDGO) in water and sediment samples using gas chromatography-tandem mass spectrometry (GC-MS/MS) ...

Evidence for in situ ethanolamine phospholipid adducts with hydroxy-alkenals.

J. Lipid Res. 48(4) , 816-25, (2007)

Hydroxy-alkenals, such as 4-hydroxy-2(E)-nonenal (4-HNE; from n-6 fatty acids), are degradation products of fatty acid hydroperoxides, including those generated by free radical attack of membrane poly...

The kynurenine metabolic pathway in the eye: studies on 3-hydroxykynurenine, a putative cataractogenic compound.

FEBS Lett. 453(1-2) , 197-200, (1999)

The rabbit lens has an elevated content of 3-hydroxykynurenine (30HKYN) in spite of a very low activity of the enzymes leading to its synthesis. The iris/ciliary body, on the contrary, has very high a...