2,4,6-Trimethylbenzene-1-sulfonohydrazide
Names
[ CAS No. ]:
16182-15-3
[ Name ]:
2,4,6-Trimethylbenzene-1-sulfonohydrazide
[Synonym ]:
EINECS 240-319-4
2,4,6-trimethylbenzenesulfonohydrazide
2-Mesitylenesulfonyl Hydrazide
2,4,6-Trimethylbenzenesulfonyl Hydrazide
MFCD00007585
Chemical & Physical Properties
[ Density]:
1.217g/cm3
[ Boiling Point ]:
369.1ºC at 760mmHg
[ Melting Point ]:
112-114 °C (dec.)(lit.)
[ Molecular Formula ]:
C9H14N2O2S
[ Molecular Weight ]:
214.28500
[ Flash Point ]:
177ºC
[ Exact Mass ]:
214.07800
[ PSA ]:
80.57000
[ LogP ]:
2.93580
[ Vapour Pressure ]:
1.21E-05mmHg at 25°C
[ Index of Refraction ]:
1.557
[ Storage condition ]:
2-8°C
MSDS
Safety Information
[ Symbol ]:
GHS02, GHS07
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H228-H315-H319-H335
[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
[ Hazard Codes ]:
F: Flammable;Xi: Irritant;
[ Risk Phrases ]:
R5
[ Safety Phrases ]:
S16-S26-S36
[ RIDADR ]:
UN 1325 4.1/PG 2
[ WGK Germany ]:
3
[ Packaging Group ]:
III
[ Hazard Class ]:
4.1
[ HS Code ]:
2935009090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2935009090
[ Summary ]:
2935009090 other sulphonamides VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:35.0%
Articles
Synlett 2011(15) , 2211-13, (2011)
A model system for the synthesis of complanadine alkaloids by "diverted Kondrat'eva" oxazole-olefin cycloaddition.
J. Org. Chem. 78(12) , 6253-63, (2013)
A synthetic approach to complanadine alkaloids is described which employs a Kondrat'eva reaction to construct the pyridine rings. The viability of this approach is demonstrated by its application to a...