2,7-Dibromofluorene
Names
[ CAS No. ]:
16433-88-8
[ Name ]:
2,7-Dibromofluorene
[Synonym ]:
2,7-Dibromo-9H-fluorene
MFCD00019048
9H-Fluorene, 2,7-dibromo-
2,7-Dibromofluorene
L B656 HHJ EE KE
Fluorene, 2,7-dibromo-
Chemical & Physical Properties
[ Density]:
1.8±0.1 g/cm3
[ Boiling Point ]:
402.7±38.0 °C at 760 mmHg
[ Melting Point ]:
164-166 °C(lit.)
[ Molecular Formula ]:
C13H8Br2
[ Molecular Weight ]:
324.011
[ Flash Point ]:
230.9±26.0 °C
[ Exact Mass ]:
321.899261
[ LogP ]:
5.71
[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C
[ Index of Refraction ]:
1.691
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi:Irritant
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S37/39
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2903999090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2903999090
[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
Articles
Nat. Protoc. 1(4) , 1698-702, (2006)
We describe the synthesis of poly[9,9'-bis(6''-N,N,N-trimethylammonium)hexyl)fluorene-co-alt-4,7-(2,1,3-benzothiadiazole) dibromide] (PFBT), a cationic, water-soluble conjugated polymer used in label-...
Self-encapsulation of poly-2,7-fluorenes in a dendrimer matrix.J. Am. Chem. Soc. 123(29) , 6965-72, (2001)
The synthesis and characterization of complex dendritic, rigid rod poly-2,7-fluorene homopolymers and copolymers via a macromonomer approach is reported. Several 2,7-dibromofluorene monomers containin...
Nearly pure blue photoluminescent poly(2,7-[9-)3,5-bis[3,5- bis(benzyloxy)benzyloxy]benzyl)-9-(3,6-dioxaoctyl)]fluorene) in film.Chem. Commun. (Camb.) (23) , 2426-7, (2001)
The first unsymmetrically substituted polyfluorene bearing a bulky poly(benzyl ether) dendron and less bulky 3,6-dioxaoctyl groups in the 9-position was designed and synthesized, which gives almost a ...