Dimethyl 2-ethylidenemalonate

Names

[ CAS No. ]:
17041-60-0

[ Name ]:
Dimethyl 2-ethylidenemalonate

[Synonym ]:
MFCD00008447
dimethyl 2-ethylidenepropanedioate

Chemical & Physical Properties

[ Density]:
1.111 g/mL at 25ºC(lit.)

[ Boiling Point ]:
153.7ºC at 760 mmHg

[ Molecular Formula ]:
C₇H₁₀O₄

[ Molecular Weight ]:
158.15200

[ Flash Point ]:
97ºC

[ Exact Mass ]:
158.05800

[ PSA ]:
52.60000

[ LogP ]:
0.27870

[ Vapour Pressure ]:
3.3mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.447(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Hazard Codes ]:
Xn

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2917190090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2917190090

[ Summary ]:
2917190090 acyclic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Catalytic asymmetric Michael reactions with enamides as nucleophiles.

Angew. Chem. Int. Ed. Engl. 46(41) , 7803-5, (2007)

Novel synthesis of conjugated dienes attached to a quaternary carbon center via Pd(0)-catalyzed deconjugative allylation of alkenylidenemalonates.

J. Org. Chem. 68(25) , 9858-60, (2003)

Palladium(0)-catalyzed deconjugative allylation of alkenylidenemalonates and alkylidenemalonates was achieved for the first time. Reactions of dimethyl 2-((E)-but-2-enylidene)malonate with various all...

Carbon-carbon bond forming reactions of N-bound transition metal a-cyanocarbanions: a mechanistic probe for catalytic Michael reactions of nitriles Naota T, et al.

Chem. Commun. (Camb.) 1 , 63-64, (2001)