3-Methylbenzoylchloride

Names

[ Name ]:
3-Methylbenzoylchloride

[Synonym ]:
3-Methyl benzoylchloride
Benzoyl chloride,3-methyl
m-Methylbenzoyl chloride
meta-methyl benzoyl chloride
m-Toluoyl chloride
3-Methylbenzoyl chloride
3-Methylbenzoylchloride
3-methyl-benzoyl chloride
Benzoyl chloride, 3-methyl-
Toluoyl chloride
m-Toluyl chloride
3-Toluoyl chloride
MFCD00000681
3-methylbenzoic acid chloride
EINECS 216-976-8

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
220.2±9.0 °C at 760 mmHg

[ Melting Point ]:
-23°C

[ Molecular Formula ]:
C₈H₇ClO

[ Molecular Weight ]:
154.594

[ Flash Point ]:
90.8±11.9 °C

[ Exact Mass ]:
154.018539

[ PSA ]:
17.07000

[ LogP ]:
2.67

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.538

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DM6644000

CHEMICAL NAME :: Benzoyl chloride, 3-methyl-

CAS REGISTRY NUMBER :: 1711-06-4

BEILSTEIN REFERENCE NO. :: 0878419

LAST UPDATED :: 199701

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C8-H7-Cl-O

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 3440 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 55(7),93,1990

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1860 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 55(7),93,1990

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S24/25-S45-S36/37/39-S27-S26-S23

[ RIDADR ]:
3265

[ RTECS ]:
DM6644000

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2916399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2916399090

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Improved HPLC determination of aliphatic amines in air by diffusion and derivatization techniques. Possanzini M and Di Palo V.

Chromatographia 29(3-4) , 151-154, (1990)

Determination of atmospheric ammonia as m-toluamide by denuder sampling and HPLC-UV detection. Possanzini M and Di Palo V.

Chromatographia 28(1-2) , 27-30, (1989)