5-Bromosalicylaldehyde
Names
[ CAS No. ]:
1761-61-1
[ Name ]:
5-Bromosalicylaldehyde
[Synonym ]:
EINECS 217-167-2
MFCD00003330
5-Bromo-2-hydroxybenzaldehyde
5-Bromosalicylaldehyde
Benzaldehyde, 5-bromo-2-hydroxy-
Chemical & Physical Properties
[ Density]:
1.7±0.1 g/cm3
[ Boiling Point ]:
247.3±20.0 °C at 760 mmHg
[ Melting Point ]:
102-106 °C(lit.)
[ Molecular Formula ]:
C7H5BrO2
[ Molecular Weight ]:
201.017
[ Flash Point ]:
103.4±21.8 °C
[ Exact Mass ]:
199.947281
[ PSA ]:
37.30000
[ LogP ]:
2.72
[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C
[ Index of Refraction ]:
1.657
[ Storage condition ]:
Room temperature.
[ Water Solubility ]:
insoluble
MSDS
Safety Information
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi: Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S36
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2942000000
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2913000090
[ Summary ]:
HS: 2913000090 halogenated, sulphonated, nitrated or nitrosated derivatives of products of heading 2912 Educational tariff:17.0% Tax rebate rate:9.0% Regulatory conditions:none Most favored nation tariff:5.5% General tariff:30.0%
Articles
Eur. J. Med. Chem. 89 , 59-66, (2014)
The title monomeric Pd(II) compound, [Pd(L)(Cl)], was synthesized in moderate yield out of the reaction of equimolar proportion of Na2[PdCl4] and 3-[(5-bromo-2-hydroxy-benzylidene)-hydrazono]-butan-2-...
Synthesis and characterization of 1,2-bis(2-(5-bromo-2-hydroxybenzilidenamino)-4-chlorophenoxy)ethane and its metal complexes: an experimental, theoretical, electrochemical, antioxidant and antibacterial study.Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 118 , 632-42, (2014)
A new Schiff base ligand was synthesized by reaction of 5-bromosalicylaldehyde with 1,2-bis(4-chloro-2-aminophenoxy)ethane. Then the Schiff base complexes were synthesized by the reaction of metal sal...
Redox-active tetrahydrosalen (salan) complexes of titanium.Dalton Trans. 40(43) , 11458-68, (2011)
A diarylamino-substituted N-methyl tetrahydrosalen (salan) ligand, (An2N)LH(2), is prepared in four steps and overall 53% yield from 5-bromosalicylaldehyde, with the key step a palladium-catalysed Har...