zirconium(iv) ethoxide

Names

[ Name ]:
zirconium(iv) ethoxide

[Synonym ]:
Aethanol,Zirkonium-tetraaethylat
ethanol,zirconium-tetraethylate
zirconium ethoxide
zirconium ethanolate
Zirconium(IV) ethoxide
Tetraethoxyzirconium
Zirconium tetraethoxide
Tetraethyl zirconate
MFCD00015654

Chemical & Physical Properties

[ Boiling Point ]:
235ºC5 mm Hg(lit.)

[ Melting Point ]:
200ºC

[ Molecular Formula ]:
C₈H₂₀O₄Zr

[ Molecular Weight ]:
271.46600

[ Flash Point ]:
235°C/5mm

[ Exact Mass ]:
270.04100

[ PSA ]:
36.92000

[ LogP ]:
1.94880

[ Vapour Pressure ]:
82.8mmHg at 25°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H228-H315-H319-H335

[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
Xi:Irritant;F:Flammable;

[ Risk Phrases ]:
R11;R36/37/38

[ Safety Phrases ]:
S26

[ RIDADR ]:
UN 3181

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
4.1

[ HS Code ]:
2901100000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2901100000

[ Summary ]:
2901100000 saturated acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%

Articles

Synthesis of Zirconium Aryloxide Complexes Containing Pendent Vinyl Groups.

Inorg. Chem. 38 , 1160, (1999)

The attachment of pendent olefin groups to oxygen-ligated zirconium complexes using olefin-substituted phenols and alcohols and readily accessible zirconium reagents is described. Syntheses of three c...