2,2-dimethylpropyl carbonochloridate
Names
[ CAS No. ]:
20412-38-8
[ Name ]:
2,2-dimethylpropyl carbonochloridate
[Synonym ]:
2,2-dimethylpropyl chlorocarbonate
2,2-dimethyl-propyl chloroformate
neo-pentyl chloroformate
Chloroformic acid neopentyl ester
MFCD00274354
Chemical & Physical Properties
[ Density]:
1.003 g/mL at 25ºC(lit.)
[ Boiling Point ]:
55ºC36 mm Hg(lit.)
[ Molecular Formula ]:
C6H11ClO2
[ Molecular Weight ]:
150.60300
[ Flash Point ]:
32ºC
[ Exact Mass ]:
150.04500
[ PSA ]:
26.30000
[ LogP ]:
2.40790
[ Vapour Pressure ]:
3.64mmHg at 25°C
[ Index of Refraction ]:
n20/D 1.410(lit.)
MSDS
Safety Information
[ Symbol ]:
GHS02, GHS05, GHS06
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H226-H314-H331
[ Precautionary Statements ]:
P210-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P403 + P233
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
T: Toxic;
[ Risk Phrases ]:
R10
[ Safety Phrases ]:
16-26-36/37/39-45
[ RIDADR ]:
UN 2742 6.1/PG 2
[ HS Code ]:
2915900090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2915900090
[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%
Articles
Int. J. Mol. Sci. 12(2) , 1161-74, (2011)
The specific rates of solvolysis of neopentyl chloroformate (1) have been determined in 21 pure and binary solvents at 45.0 °C. In most solvents the values are essentially identical to those for ethyl...
Alkylation of alkenes: ethylaluminum sesquichloride-mediated hydro-alkyl additions with alkyl chloroformates and di-tert-butylpyrocarbonate.J. Am. Chem. Soc. 126(33) , 10319-30, (2004)
A general method for the hydro-alkyl addition to the nonactivated C=C double bond of alkenes using alkyl chloroformates (primary, secondary), 12, and di-tert-butylpyrocarbonate, 52, mediated by ethyla...