2-Bromomalonaldehyde

Names

[ CAS No. ]:
2065-75-0

[ Name ]:
2-Bromomalonaldehyde

[Synonym ]:
Malonaldehyde,bromo
2-bromo-1,3-propanedial
BrCH(CHO)2
Propanedial, 2-bromo-
2-brommalondialdehyd
propanedial, bromo-
Bromomalonaldehyde
Bromomalondialdehyde
Malonaldehyde, bromo-
MFCD00459999
2-Bromomalonaldehyde
2-bromomalondialdehyde
PROPANEDIAL,BROMO
2-bromo-malonaldehyde

Chemical & Physical Properties

[ Density]:
1.8±0.1 g/cm3

[ Boiling Point ]:
134.8±25.0 °C at 760 mmHg

[ Melting Point ]:
132-136 °C(lit.)

[ Molecular Formula ]:
C₃H₃BrO₂

[ Molecular Weight ]:
150.959

[ Flash Point ]:
69.5±9.7 °C

[ Exact Mass ]:
149.931641

[ PSA ]:
34.14000

[ LogP ]:
0.96

[ Vapour Pressure ]:
8.0±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.469

[ Storage condition ]:
Keep Cold

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2913000090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2913000090

[ Summary ]:
HS: 2913000090 halogenated, sulphonated, nitrated or nitrosated derivatives of products of heading 2912 Educational tariff:17.0% Tax rebate rate:9.0% Regulatory conditions:none Most favored nation tariff:5.5% General tariff:30.0%

Articles

Reactions of 9-substituted guanines with bromomalondialdehyde in aqueous solution predominantly yield glyoxal-derived adducts.

Org. Biomol. Chem. 2 , 1943-1950, (2004)

Reactions of 9-ethylguanine, 2'-deoxyguanosine and guanosine with bromomalondialdehyde in aqueous buffers over a wide pH-range were studied. The main products were isolated and characterized by (1)H a...

A simplified and efficient synthesis of 5,10-dideaza-5,6,7,8-tetrahydrofolic acid (DDATHF).

Invest. New Drugs 14(3) , 281-5, (1996)

A new and extremely efficient synthesis of DDATHF from 4-vinylbenzoic acid and bromomalondialdehyde as precursors has been developed which proceeds in 48% overall yield.

Formation of ethenocarbaldehyde derivatives of adenosine and cytidine in reactions with mucochloric acid.

Chem. Res. Toxicol. 6(4) , 495-9, (1993)

Mucochloric acid, a genotoxic compound formed during chlorine disinfection of drinking water, was reacted with adenosine and cytidine at pH 4.0, 90 degrees C. HPLC analyses with UV detection at 325 nm...