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Silver oxide

Names

[ CAS No. ]:
20667-12-3

[ Name ]:
Silver oxide

[Synonym ]:
(argentiooxy)silver
silver(l) oxide
Disilver oxide
Silver(1+) oxide
Silver(I) oxide
silver hemioxide
Silver oxide
silver oxide (I)
Silver oxide (Ag2O)
Silver (I) Oxide
EINECS 243-957-1
MFCD00003404
Argentous oxide

Chemical & Physical Properties

[ Density]:
7,143 g/cm3

[ Melting Point ]:
300°C (dec.)

[ Molecular Formula ]:
Ag2O

[ Molecular Weight ]:
231.736

[ Exact Mass ]:
229.805099

[ PSA ]:
9.23000

[ Stability ]:
Stable. Oxidiser. Incompatible with most common metals, ammonia, magnesium, many organic materials.

[ Water Solubility ]:
slightly soluble

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
VW4900000
CHEMICAL NAME :
Silver(1+) oxide
CAS REGISTRY NUMBER :
20667-12-3
LAST UPDATED :
199712
DATA ITEMS CITED :
20
MOLECULAR FORMULA :
Ag2-O
MOLECULAR WEIGHT :
231.74
WISWESSER LINE NOTATION :
AG2 O

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2820 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
70 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 27(12),33,1983
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1027 mg/kg
TOXIC EFFECTS :
Behavioral - tetany Lungs, Thorax, or Respiration - cyanosis Gastrointestinal - hypermotility, diarrhea
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 27(12),33,1983
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
37 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 27(12),33,1983 *** REVIEWS *** ACGIH TLV-TWA 0.01 mg(Ag)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.01 mg(Ag)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,231,1971 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.01 mg(Ag)/m3 JAN 1993 OEL-AUSTRALIA:TWA 0.01 mg(Ag)/m3 JAN 1993 OEL-BELGIUM:TWA 0.01 mg(Ag)/m3 JAN 1993 OEL-DENMARK:TWA 0.01 mg(Ag)/m3 JAN 1993 OEL-FINLAND:TWA 0.01 mg(Ag)/m3;STEL 0.03 mg(Ag)/m3;Skin JAN 1993 OEL-THE NETHERLANDS:TWA 0.01 mg(Ag)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.01 mg(Ag)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.01 mg(Ag)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.01 mg(Ag)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X2953 No. of Facilities: 22 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 269 (estimated) No. of Female Employees: 22 (estimated)

Safety Information

[ Symbol ]:

GHS03, GHS05, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H271-H318-H410

[ Precautionary Statements ]:
P220-P273-P280-P305 + P351 + P338-P501

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
O: Oxidizing agent;C: Corrosive;

[ Risk Phrases ]:
R34;R8

[ Safety Phrases ]:
S17-S26-S36-S45-S36/37/39

[ RIDADR ]:
UN 1479 5.1/PG 2

[ WGK Germany ]:
2

[ RTECS ]:
VW4900000

[ Packaging Group ]:
II

[ Hazard Class ]:
5.1

Synthetic Route

Precursor & DownStream

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An ultrasonic reaction of Ag(2)O, 4,4'-bipyridine (bipy) and (2S, 3R)-3-amino-2-hydroxybutanoic acid (L-Thr) gives an unexpected Ag(I) supramolecular framework, {[Ag(3)(bipy)(3)(cahba)]·HCO(3)·10H(2)O...

Toxicity of silver nanoparticles at the air-liquid interface.

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