adamantanecarbonyl chloride

Names

[ CAS No. ]:
2094-72-6

[ Name ]:
adamantanecarbonyl chloride

[Synonym ]:
EINECS 218-252-7
Adamantane-1-carbonyl chloride
1-Adamantanecarboxlic acid chloride
adamantanecarboxylic acid chloride
1-Adamantanoic acid chloride
adamantanecarbonyl chloride
Tricyclo[3.3.1.1]decane-1-carbonyl chloride
MFCD00074724
1-AdamantanecarbonylChloride
Adamantane-1-carboxylic acid chloride
1-Adamantanecarbonyl chloride
1-Adamantyl carbonyl chloride
1-Adamantanecarboxylic acid chloride
1-Adamantoyl chloride
1-ADAMANTYLCARBONYL CHLORIDE
Adamantoyl chloride

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
270.6±0.0 °C at 760 mmHg

[ Melting Point ]:
49-51 °C(lit.)

[ Molecular Formula ]:
C₁₁H₁₅ClO

[ Molecular Weight ]:
198.689

[ Flash Point ]:
139.0±8.3 °C

[ Exact Mass ]:
198.081146

[ PSA ]:
17.07000

[ LogP ]:
3.34

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.556

[ Storage condition ]:
2-8°C

[ Water Solubility ]:
may decompose

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R14;R34;R37

[ Safety Phrases ]:
S26-S36/37/39-S45-S24/25

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2915900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Articles

Efficient preparation of amine-modified oligodeoxynucleotide using modified H-phosphonate chemistry for DNA microarray fabrication.

Anal. Bioanal. Chem 387(6) , 2027-35, (2007)

Amine-modified oligodeoxynucleotides (AMO) are commonly used probe oligodeoxynucleotides for DNA microarray preparation. Two methods are currently used for AMO preparation--use of amine phosphoramidit...

Novel activating and capping reagents for improved hydrogen-phosphonate DNA synthesis. Andrus A, et al.

Tetrahedron Lett. 29(8) , 861-864, (1988)

Highly selective catalytic Friedel-Crafts acylation and sulfonylation of activated aromatic compounds using indium metal. Jang DO, et al.

Tetrahedron Lett. 47(34) , 6063-6066, (2006)