3-Bromofuran
Names
[ CAS No. ]:
22037-28-1
[ Name ]:
3-Bromofuran
[Synonym ]:
EINECS 244-744-6
3-bromofurane
Furan,3-bromo
3-bromo-furan
3-furan bromide
Furan, 3-bromo-
3-Furyl bromide
MFCD00005347
3-Brom-furan
3-Bromofuran
4-bromofuran
Chemical & Physical Properties
[ Density]:
1.7±0.1 g/cm3
[ Boiling Point ]:
103.0±0.0 °C at 760 mmHg
[ Molecular Formula ]:
C4H3BrO
[ Molecular Weight ]:
146.970
[ Flash Point ]:
3.3±0.0 °C
[ Exact Mass ]:
145.936722
[ PSA ]:
13.14000
[ LogP ]:
2.18
[ Vapour Pressure ]:
38.0±0.1 mmHg at 25°C
[ Index of Refraction ]:
1.505
[ Storage condition ]:
−20°C
MSDS
Safety Information
[ Symbol ]:
GHS02
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H225
[ Precautionary Statements ]:
P210
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
F:Flammable;Xi:Irritant;
[ Risk Phrases ]:
R11;R36/37/38
[ Safety Phrases ]:
S16-S23-S24/25-S37/39-S26
[ RIDADR ]:
UN 1993 3/PG 2
[ WGK Germany ]:
3
[ Packaging Group ]:
II
[ Hazard Class ]:
3
[ HS Code ]:
2932190090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2932190090
[ Summary ]:
2932190090 other compounds containing an unfused furan ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%
Articles
Bioorg. Chem. 31(1) , 68-79, (2003)
Diels-Alder addition of furans (furan, furfuryl alcohol, and 3-bromofuran) to maelic anhydride yields three distinct 5,6-dehydronorcantharidins. Hydrogenation of (4,10-dioxatricyclo[5.2.1.0]decane-3,5...
Addition/oxidative rearrangement of 3-furfurals and 3-furyl imines: new approaches to substituted furans and pyrroles.J. Am. Chem. Soc. 130(12) , 4097-104, (2008)
Furans and pyrroles are important synthons in chemical synthesis and are commonly found in natural products, pharmaceutical agents, and materials. Introduced herein are three methods to prepare 2-subs...