(|R|)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine
Names
[ CAS No. ]:
221012-82-4
[ Name ]:
(|R|)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine
[Synonym ]:
(R)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine
MFCD04038734
Chemical & Physical Properties
[ Boiling Point ]:
686.1ºC at 760 mmHg
[ Melting Point ]:
261-265ºC
[ Molecular Formula ]:
C38H34N2O4P2
[ Molecular Weight ]:
644.63500
[ Flash Point ]:
368.7ºC
[ Exact Mass ]:
644.19900
[ PSA ]:
89.88000
[ LogP ]:
5.69440
[ Vapour Pressure ]:
6.72E-18mmHg at 25°C
MSDS
Safety Information
[ Hazard Codes ]:
Xi
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S36/37/39
[ RIDADR ]:
NONH for all modes of transport
Articles
Acc. Chem. Res. 39 , 711, (2006)
This Account outlines our efforts in the design and synthesis of a family of highly effective atropisomeric dipyridylphosphine ligands (P-Phos and its variants) and in the development of their widespr...