Methyl 5-Methylsalicylate

Names

[ Name ]:
Methyl 5-Methylsalicylate

[Synonym ]:
Methyl 2-hydroxy-5-methylbenzoate
MFCD00016485
Methyl-5-Methylsalicylate
Methyl-6-hydroxy-m-toluat
Methylsalicylic acid methyl ester
methyl 5-methylsalicilate
5-methylsalicylic acid methyl ester
P-CRESOTIC ACID METHYL ESTER
2-Hydroxy-5-methylbenzoic Acid Methyl Ester
Benzoic acid, 2-hydroxy-5-methyl-, methyl ester
2,5-Cresoticacid,methylester
2-hydroxy-5-methyl-benzoic acid methyl ester
EINECS 245-173-5
Methyl-5-Methyl Salicylate
methyl 6-hydroxy-m-toluate
6-Hydroxy-m-toluic Acid Methyl Ester
RARECHEM AL BF 0811

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
242.4±20.0 °C at 760 mmHg

[ Melting Point ]:
2ºC

[ Molecular Formula ]:
C₉H₁₀O₃

[ Molecular Weight ]:
166.174

[ Flash Point ]:
98.5±14.5 °C

[ Exact Mass ]:
166.062988

[ PSA ]:
46.53000

[ LogP ]:
2.69

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.542

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
2

[ HS Code ]:
2918290000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Preparation

Customs

[ HS Code ]: 2918290000

[ Summary ]:
HS: 2918290000 other carboxylic acids with phenol function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) VAT:17.0% MFN tariff:6.5% General tariff:30.0%

Articles

Effective photosensitized energy transfer of nonanuclear terbium clusters using methyl salicylate derivatives.

J. Phys. Chem. A 119(10) , 1943-7, (2015)

The photophysical properties of the novel nonanuclear Tb(III) clusters Tb-L1 and Tb-L2 involving the ligands methyl 4-methylsalicylate (L1) and methyl 5-methylsalicylate (L2) are reported. The positio...

Methyl 6-methylsalicylate: a female-produced pheromone component of the parasitoid wasp Spalangia endius.

J. Chem. Ecol. 36(10) , 1140-7, (2010)

Sex-pheromone-related behavior and chemistry were studied in the wasp Spalangia endius Walker (Hymenoptera: Pteromalidae), a pupal parasitoid of the house fly, Musca domestica L. (Diptera: Muscidae). ...

Conjugate addition to 3-arylsulfinylchromones as a synthetic route to homochiral 2-substituted chromanones: scope and limitations. Hodgetts KJ, et al.

Tetrahedron 57(31) , 6793-6804, (2001)